Ethoxyethene

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Names

[ CAS No. ]:
109-92-2

[ Name ]:
Ethoxyethene

[Synonym ]:
vinyl ethyl dichloro silane
Aethyl-dichlor-vinyl-silan
Ethyl ethenyl ether
dichloroethenylethyl-silan
ethyl vinyl ether
dichloroethylvinylsilane
4-01-00-02049 (Beilstein Handbook Reference)
1-Ethoxyethene
UNII-6235C9592H
Ether, vinyl ethyl
Silane,dichloroethenylethyl
Aethyl-vinyl-dichlorsilan
(ethoxy)ethylene
2-ethoxyethylene
Silane,dichloroethylvinyl
Ethoxyethene
ethyloxyethylene
EINECS 203-718-4
(EtO)-CH=CH2
Ethene, ethoxy-
ethenyl ethyl ether
Dichlor-aethyl-vinyl-silan
dichloroethylvinyl-silan
1-ethoxyethylene
Ethoxyethylene
Vinyl ethyl ether
ethyl-dichloro-vinyl-silane
ethylvinyldichlorosilane
MFCD00009248

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
32.5±9.0 °C at 760 mmHg

[ Melting Point ]:
−116 °C(lit.)

[ Molecular Formula ]:
C4H8O

[ Molecular Weight ]:
72.106

[ Flash Point ]:
-45.6±0.0 °C

[ Exact Mass ]:
72.057518

[ PSA ]:
9.23000

[ LogP ]:
1.04

[ Vapour Pressure ]:
581.4±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.376

[ Stability ]:
Stable. Highly flammable. Incompatible with strong oxidizing agents. May form peroxides in storage - check for their formation before use.

[ Water Solubility ]:
7.8 g/L (25 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KO0710000
CHEMICAL NAME :
Ether, ethyl vinyl
CAS REGISTRY NUMBER :
109-92-2
BEILSTEIN REFERENCE NO. :
0605351
LAST UPDATED :
199701
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C4-H8-O
MOLECULAR WEIGHT :
72.12
WISWESSER LINE NOTATION :
2O1U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
8160 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
16000 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>20 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GAFCC* GAF Material Safety Data Sheet. (GAF Chemicals Corporation, 1361 Alps Road, Wayne, NJ 07470)
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
324 gm/m3/15M
TOXIC EFFECTS :
Behavioral - general anesthetic
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>20 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
17900 ppm
REFERENCE :
ANESAV Anesthesiology. (Lippincott/Harper, Journal Fulfillment Dept., 2350 Virginia Ave., Hagerstown, MD 21740) V.1- 1940- Volume(issue)/page/year: 50,426,1979

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P305 + P351 + P338-P370 + P378-P403 + P235

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
F:Flammable

[ Risk Phrases ]:
R12;R19;R36/37/38

[ Safety Phrases ]:
S16-S23-S26-S3/7-S33-S36

[ RIDADR ]:
UN 1302 3/PG 1

[ WGK Germany ]:
1

[ RTECS ]:
KO0710000

[ Packaging Group ]:
I

[ Hazard Class ]:
3

[ HS Code ]:
2942000000

Synthetic Route

Precursor & DownStream

Precursor

  • 1,1-Diethoxyethane
  • Ethanol
  • Acetylene
  • 1-chloro-1-ethoxyethane
  • Ethoxyethyne
  • Vinyl ether
  • N-Butyl Vinyl Ether
  • (Z)-1-ethoxy-2-triphenylstannylethene
  • (Z)-1-ethoxy-2-triphenylstannylethene
  • 2-Bromoethoxyethane

DownStream

  • 2-ethoxy-6-methyl-4-phenyl-3,4-dihydro-2H-pyran
  • methyl 4-ethoxy-2-oxobut-3-enoate
  • 2-ETHOXYCHROMAN
  • 2-(1-but-3-en-2-yl-4,4-dimethylcyclopent-2-en-1-yl)acetaldehyde
  • Benzoic acid,2-acetyl-, methyl ester
  • 3-(2-bromo-1-ethoxyethoxy)-1-methylcyclohexene
  • acetaldehyde ethyl methyl acetal
  • 4H-1,2-Oxazine-3-carboxylicacid,6-ethoxy-5,6-dihydro-,ethylester(9CI)
  • bis(4-methylphenyl)mercury
  • 4,4,4-Trifluorobutanal

Customs

[ HS Code ]: 2909199090

[ Summary ]:
2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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Related Compounds

  • 1-bromo-2-ethoxyethene
  • 1-bromo-1-ethoxyethene
  • 1-Chloro-2-ethoxyethene
  • 2-phenyl-1-ethoxyethene
  • 2-phenyl-1-ethoxyethene
  • 1-chloro-1-ethoxyethene
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 2-[1-(aminomethyl)-3-hydroxy-cyclobutyl]-6-bromo-phenol
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 5-(2,4-Difluorophenyl)-1,2,3,6-tetrahydropyridin-3-ol
  • Methyl 2-chloro-5-(fluorosulfonyl)benzoate
  • 2-(1-{2-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclohexyl]acetamido}cyclopropyl)acetic acid
  • 2-(1-{[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)acetamido]methyl}cyclohexyl)acetic acid
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol