Maleic acid

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Names

[ CAS No. ]:
110-16-7

[ Name ]:
Maleic acid

[Synonym ]:
(2Z)-2-Butenedioic acid
2-Butenedioic acid, (2Z)-
cis-2-Butenedioic Acid
2-Butenedioicacid (2Z)-
MFCD00063177
EINECS 203-742-5
Maleic acid
cis-Butenedioic acid,Toxilic acid
Maleic acid [NA2215]
(2Z)-But-2-enedioic acid

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
355.5±25.0 °C at 760 mmHg

[ Melting Point ]:
134-138ºC

[ Molecular Formula ]:
C4H4O4

[ Molecular Weight ]:
116.072

[ Flash Point ]:
183.0±19.7 °C

[ Exact Mass ]:
116.010956

[ PSA ]:
74.60000

[ LogP ]:
-0.01

[ Vapour Pressure ]:
0.0±1.7 mmHg at 25°C

[ Index of Refraction ]:
1.526

[ Storage condition ]:
Store at RT.

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents, bases.

[ Water Solubility ]:
790 g/L (25 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OM9625000
CHEMICAL NAME :
Maleic acid
CAS REGISTRY NUMBER :
110-16-7
BEILSTEIN REFERENCE NO. :
0605762
LAST UPDATED :
199710
DATA ITEMS CITED :
13
MOLECULAR FORMULA :
C4-H4-O4
MOLECULAR WEIGHT :
116.08
WISWESSER LINE NOTATION :
QV1U1VQ -C

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
708 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Behavioral - muscle weakness Gastrointestinal - ulceration or bleeding from stomach
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>720 mg/m3/1H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2400 mg/kg
TOXIC EFFECTS :
Tumorigenic - active as anti-cancer agent
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1560 mg/kg
TOXIC EFFECTS :
Behavioral - tremor

MUTATION DATA

TYPE OF TEST :
DNA inhibition
TEST SYSTEM :
Human Fibroblast
DOSE/DURATION :
20 mmol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 183,89,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84505 No. of Facilities: 1840 (estimated) No. of Industries: 22 No. of Occupations: 27 No. of Employees: 17036 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84505 No. of Facilities: 2076 (estimated) No. of Industries: 36 No. of Occupations: 45 No. of Employees: 30064 (estimated) No. of Female Employees: 11590 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302 + H312-H315-H317-H318-H335

[ Precautionary Statements ]:
P280-P301 + P312 + P330-P305 + P351 + P338 + P310

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S28-S37

[ RIDADR ]:
UN 2215

[ WGK Germany ]:
1

[ RTECS ]:
OM9625000

[ Packaging Group ]:
III

[ HS Code ]:
2917190090

Precursor & DownStream

Precursor

DownStream

  • bis[1-[3-[2-(1-oxobutyl)-10H-phenothiazin-2-yl]propyl]-4-methylpiperazin-1-yl] maleate
  • S-(1,2-Dicarboxyethyl)glutathione
  • fumaric acid
  • 3-Hydroxyaspartic Acid
  • Glycine
  • methylamine
  • DL-Aspartic Acid
  • DL-Alanine
  • beta-Alanine
  • (betaR)-beta-Cyclopentyl-4-(7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazole-1-propanenitrile (2Z)-2-butenedioate

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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  • maleic acid imide
  • fluoromaleic acid
  • i-amylmaleic acid
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