Methyl (2R)-3-bromo-2-methylpropanoate

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Names

[ CAS No. ]:
110556-33-7

[ Name ]:
Methyl (2R)-3-bromo-2-methylpropanoate

[Synonym ]:
(R)-(+)-3-Bromo-2-Methylpropionic Acid Methyl Ester
(R)-(+)-3-Bromoisobutyric Acid Methyl Ester
MFCD00010639
Methyl (R)-(+)-3-BroMoisobutyrate
METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE
Methyl (2R)-3-bromo-2-methylpropanoate
Propanoic acid, 3-bromo-2-methyl-, methyl ester, (2R)-

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
173.7±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C5H9BrO2

[ Molecular Weight ]:
181.028

[ Flash Point ]:
73.9±0.0 °C

[ Exact Mass ]:
179.978592

[ PSA ]:
26.30000

[ LogP ]:
1.50

[ Vapour Pressure ]:
1.3±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.454

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (S)-Roche ester
  • (S)-3-methanesulfonyloxy-2-methyl-propionic acid methyl ester
  • (R)-Roche ester
  • methyl (2S)-3-acetyloxy-2-methylpropanoate
  • Methyl 3-bromo-2-methylpropanoate
  • diazomethane
  • acetic acid,(2R)-2-methylbut-3-en-1-ol

DownStream

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • Methyl 3-bromo-2-methylpropanoate
  • methyl (2R)-3-azido-2-methylpropanoate
  • Methyl 3-bromo-2-methoxy-2-methylpropanoate
  • methyl 3-bromo-2-oxo-1-cycloheptanecarboxylate
  • Methyl 3-bromo-2-(bromomethyl)propanoate
  • methyl 3-bromo-2,3,3-trichloropropanoate
  • 2-chloro-3-(4-methanesulfonyl-1H-pyrazol-1-yl)propanoic acid
  • 1-(3-chloro-3,3-difluoropropyl)-5-methyl-1H-pyrazol-3-amine
  • 1H,2H,3H,4H,9H-pyrido[3,4-b]indole-5-carbaldehyde
  • 1-(3-chloro-3,3-difluoropropyl)-3-methyl-1H-pyrazol-4-amine
  • 3-(3-amino-5-bromo-1H-1,2,4-triazol-1-yl)propane-1-sulfonic acid
  • 4-(3-amino-5-bromo-1H-1,2,4-triazol-1-yl)butane-1-sulfonic acid
  • 1H,2H,3H,4H,9H-pyrido[3,4-b]indole-6-carbaldehyde
  • 1-[2-amino-4-(4-methanesulfonyl-1H-pyrazol-1-yl)phenyl]ethan-1-one
  • propan-2-yl 2-(4-amino-1H-imidazol-1-yl)acetate
  • 2-{5-Chloro-7-cyclopropyl-[1,2,4]triazolo[1,5-a]pyridin-2-yl}pyrrolidine
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