Methyl (2R)-3-bromo-2-methylpropanoate

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Names

[ CAS No. ]:
110556-33-7

[ Name ]:
Methyl (2R)-3-bromo-2-methylpropanoate

[Synonym ]:
(R)-(+)-3-Bromo-2-Methylpropionic Acid Methyl Ester
(R)-(+)-3-Bromoisobutyric Acid Methyl Ester
MFCD00010639
Methyl (R)-(+)-3-BroMoisobutyrate
METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE
Methyl (2R)-3-bromo-2-methylpropanoate
Propanoic acid, 3-bromo-2-methyl-, methyl ester, (2R)-

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
173.7±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C5H9BrO2

[ Molecular Weight ]:
181.028

[ Flash Point ]:
73.9±0.0 °C

[ Exact Mass ]:
179.978592

[ PSA ]:
26.30000

[ LogP ]:
1.50

[ Vapour Pressure ]:
1.3±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.454

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (S)-Roche ester
  • (S)-3-methanesulfonyloxy-2-methyl-propionic acid methyl ester
  • (R)-Roche ester
  • methyl (2S)-3-acetyloxy-2-methylpropanoate
  • Methyl 3-bromo-2-methylpropanoate
  • diazomethane
  • acetic acid,(2R)-2-methylbut-3-en-1-ol

DownStream

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • Methyl 3-bromo-2-methylpropanoate
  • methyl (2R)-3-azido-2-methylpropanoate
  • Methyl 3-bromo-2-methoxy-2-methylpropanoate
  • methyl 3-bromo-2-oxo-1-cycloheptanecarboxylate
  • Methyl 3-bromo-2-(bromomethyl)propanoate
  • methyl 3-bromo-2,3,3-trichloropropanoate
  • Bispyrithione magsulfex
  • Sulbactam benzathine
  • Pirenzepine hydrochloride monohydrate
  • (S)-4-Ethyl-4-hydroxy-3,14-dioxo-3,4,12,14-tetrahydro-1H-pyrano[3',4':6,7]indolizino[1,2-b]quinoline-11-carbaldehyde O-(2-aminoethyl) oxime hydrochloride
  • 2-Benzofurancarboxamide, N,N-dimethyl-
  • [2-(Isonicotinoylamino)-1,3-thiazol-4-yl]acetic acid
  • 5-Iodo-4-methyl-2-nitrobenzonitrile
  • 6-Methylimidazo[2,1-b][1,3]thiazole-5-carbothioamide
  • 8-Methoxy-5,10-dihydroindeno[1,2-b]indole
  • 2-Isopropyl-2-phenylpropane-1,3-diol
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