4-Bromo-2,6-di-tert-butylphenol

Names

[ Name ]:
4-Bromo-2,6-di-tert-butylphenol

[Synonym ]:
4-bromo-2,6-ditert-butylphenol
2,6-Di-tert-butyl-4-bromophenol
EINECS 214-521-8
4-BroMo-2,6-di-tert-butylphenol
MFCD00051598

Chemical & Physical Properties

[ Density]:
1.201 g/cm3

[ Boiling Point ]:
128 °C / 4mmHg

[ Melting Point ]:
78-83 °C (dec.)(lit.)

[ Molecular Formula ]:
C₁₄H₂₁BrO

[ Molecular Weight ]:
285.22000

[ Flash Point ]:
119.4ºC

[ Exact Mass ]:
284.07800

[ PSA ]:
20.23000

[ LogP ]:
4.74970

[ Vapour Pressure ]:
0.00333mmHg at 25°C

[ Index of Refraction ]:
1.523

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2908199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2,6-Di-tert-butylphenol
4-Bromophenol
4,4-Dibromo-2,6-di-tert-butylcyclohexa-2,5-dienone
tert-butyl chloride
Methanol
4-bromo-2,6-ditert-butylcyclohexa-2,5-dien-1-one
Ethanol
Isopropanol
1-(3,5-Di-tert-butyl-4-hydroxyphenyl)-1-propanol

DownStream

2,6-Di-tert-butyl-p-benzoquinone
5-Brom-7-tert-butyl-2-methyl-benzoxazol
3,3',5,5'-Tetra-tert-butyldiphenoquinone
bis(1-bromo-3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-yl)
2,2',6,6'-Tetra-tert-butyl-4,4'-biphenol
2,4-Di-t-butylphenol
2-(3,5-ditert-butyl-4-hydroxyphenyl)sulfanylacetamide
2,6-Di-tert-butylphenol
5-Bromo-1,3-di-tert-butyl-2-methoxybenzene
2,6-ditert-butyl-4-[5-[5-(3,5-ditert-butyl-4-hydroxyphenyl)thiophen-2-yl]thiophen-2-yl]phenol

Customs

[ HS Code ]: 2908199090

[ Summary ]:
HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

Articles

Phase transfer catalyzed polymerization of 4-bromo-2, 6-dimethylphenol in the presence of a terminating comonomer phenol: 2, 4, 6-tri-tert-butylphenol or 4-bromo-2, 6-di-tert-butylphenol. Wang JH and Percec V.

Polym. Bull. 25(1) , 33-40, (1991)

Photolysis of 4-bromo-2, 6-di-tert-butylphenol in benzene solution. Lappin GR and Zannucci JS.

Tetrahedron Lett. 10(58) , 5085-5087, (1969)

Effect of donor and acceptor on the mechanism of a photochemical reaction in doped single crystals for radical pairs in 4-bromo-2, 6-di-tert-butylphenol single crystal doped with 2, 6-di-tert-butyl-p-quinone. Tipikin DS, et al.

Kinet. Catal. 42(2) , 246-250, (2001)

4-bromo-2,6-di-tert-butylphenol trimethylsilyl ether
4-Bromo-2,6-di-tert-butyl-4-isobutyl-cyclohexa-2,5-dienone
4-Benzyl-4-bromo-2,6-di-tert-butyl-cyclohexa-2,5-dienone
1-bromo-3,7-ditert-butylnaphthalene
4-butyl-2,6-di-tert-butylphenol
4-(BENZYLAMINOMETHYL)-2,6-DI-TERT-BUTYLPHENOL
1,1-Difluoro-2-methyl-3-(6-methylpyridin-2-yl)propan-2-amine
3-[(3-Ethoxy-2-methoxyphenyl)methyl]azetidine
(2R,4R)-1-{2-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-1H-pyrazol-1-yl]acetyl}-4-hydroxypyrrolidine-2-carboxylic acid
Tert-butyl 3-(2,2-dimethylthiolan-3-yl)piperazine-1-carboxylate
tert-butyl 3-[(1R)-2-amino-1-hydroxyethyl]morpholine-4-carboxylate
tert-butyl N-[(3S)-3-aminobutyl]-N-(propan-2-yl)carbamate
5-(3-tert-butyl-1-methyl-1H-pyrazol-5-yl)-1,3-oxazol-2-amine
3-Amino-2-[1-(ethoxycarbonyl)piperidin-4-yl]propanoic acid
2-Amino-3-(2-{[(tert-butoxy)carbonyl]amino}-5-fluorophenyl)-3-methylbutanoic acid
rac-(1R,6S,8R)-8-(4-fluorophenyl)-3-azabicyclo[4.2.0]octane

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