4-Bromo-2,6-di-tert-butylphenol

Suppliers

Names

[ CAS No. ]:
1139-52-2

[ Name ]:
4-Bromo-2,6-di-tert-butylphenol

[Synonym ]:
4-bromo-2,6-ditert-butylphenol
2,6-Di-tert-butyl-4-bromophenol
EINECS 214-521-8
4-BroMo-2,6-di-tert-butylphenol
MFCD00051598

Chemical & Physical Properties

[ Density]:
1.201 g/cm3

[ Boiling Point ]:
128 °C / 4mmHg

[ Melting Point ]:
78-83 °C (dec.)(lit.)

[ Molecular Formula ]:
C14H21BrO

[ Molecular Weight ]:
285.22000

[ Flash Point ]:
119.4ºC

[ Exact Mass ]:
284.07800

[ PSA ]:
20.23000

[ LogP ]:
4.74970

[ Vapour Pressure ]:
0.00333mmHg at 25°C

[ Index of Refraction ]:
1.523

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2908199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2,6-Di-tert-butylphenol
  • 4-Bromophenol
  • 4,4-Dibromo-2,6-di-tert-butylcyclohexa-2,5-dienone
  • tert-butyl chloride
  • Methanol
  • 4-bromo-2,6-ditert-butylcyclohexa-2,5-dien-1-one
  • Ethanol
  • Isopropanol
  • 1-(3,5-Di-tert-butyl-4-hydroxyphenyl)-1-propanol

DownStream

  • 2,6-Di-tert-butyl-p-benzoquinone
  • 5-Brom-7-tert-butyl-2-methyl-benzoxazol
  • 3,3',5,5'-Tetra-tert-butyldiphenoquinone
  • bis(1-bromo-3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-yl)
  • 2,2',6,6'-Tetra-tert-butyl-4,4'-biphenol
  • 2,4-Di-t-butylphenol
  • 2-(3,5-ditert-butyl-4-hydroxyphenyl)sulfanylacetamide
  • 2,6-Di-tert-butylphenol
  • 5-Bromo-1,3-di-tert-butyl-2-methoxybenzene
  • 2,6-ditert-butyl-4-[5-[5-(3,5-ditert-butyl-4-hydroxyphenyl)thiophen-2-yl]thiophen-2-yl]phenol

Customs

[ HS Code ]: 2908199090

[ Summary ]:
HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

Articles

Phase transfer catalyzed polymerization of 4-bromo-2, 6-dimethylphenol in the presence of a terminating comonomer phenol: 2, 4, 6-tri-tert-butylphenol or 4-bromo-2, 6-di-tert-butylphenol. Wang JH and Percec V.

Polym. Bull. 25(1) , 33-40, (1991)

Photolysis of 4-bromo-2, 6-di-tert-butylphenol in benzene solution. Lappin GR and Zannucci JS.

Tetrahedron Lett. 10(58) , 5085-5087, (1969)

Effect of donor and acceptor on the mechanism of a photochemical reaction in doped single crystals for radical pairs in 4-bromo-2, 6-di-tert-butylphenol single crystal doped with 2, 6-di-tert-butyl-p-quinone. Tipikin DS, et al.

Kinet. Catal. 42(2) , 246-250, (2001)


More Articles

Related Compounds

  • 4-bromo-2,6-di-tert-butylphenol trimethylsilyl ether
  • 4-Bromo-2,6-di-tert-butyl-4-isobutyl-cyclohexa-2,5-dienone
  • 4-Benzyl-4-bromo-2,6-di-tert-butyl-cyclohexa-2,5-dienone
  • 1-bromo-3,7-ditert-butylnaphthalene
  • 4-butyl-2,6-di-tert-butylphenol
  • 4-(BENZYLAMINOMETHYL)-2,6-DI-TERT-BUTYLPHENOL
  • N-[2-bromo-5-chloro-3-(trifluoromethyl)phenyl]acetamide
  • DJ2K5G8Q34
  • n-(4-Morpholinophenyl)-1-(naphthalen-1-ylmethyl)-1h-pyrazolo[3,4-d]pyrimidin-6-amine
  • 1-(2,5-Dimethylphenyl)-4-(3-pyridinylsulfonyl)piperazine
  • N-ethyl-2-nitropyridin-3-amine
  • 1-(4-Fluoro-2-methylphenyl)guanidine
  • (2R)-2-(2,3-Dihydro-1,4-benzodioxin-6-yl)propan-1-amine
  • N,N-dimethyl-2-(piperidin-4-yl)aniline dihydrochloride
  • 2-(2-Amino-6-chlorophenoxy)ethan-1-ol
  • 3-(4-Aminophenylthio)propionic acid t-butyl ester