Tris(4-chlorophenyl)phosphine

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Names

[ CAS No. ]:
1159-54-2

[ Name ]:
Tris(4-chlorophenyl)phosphine

[Synonym ]:
MFCD00013639
Tris(p-chlorophenyl)phosphine
tris(4-chlorophenyl)phosphane
Tris(4-chlorophenyl)phosphine
EINECS 214-596-7
Phosphine, tris(4-chlorophenyl)-

Chemical & Physical Properties

[ Boiling Point ]:
427.6±40.0 °C at 760 mmHg

[ Melting Point ]:
100-103 °C(lit.)

[ Molecular Formula ]:
C18H12Cl3P

[ Molecular Weight ]:
365.621

[ Flash Point ]:
212.4±27.3 °C

[ Exact Mass ]:
363.974213

[ PSA ]:
13.59000

[ LogP ]:
7.47

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
3278

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Phosphine oxide, tris(4-chlorophenyl)- (9CI)
  • 4-Bromochlorobenzene
  • bromozinc(1+),chlorobenzene
  • 4-chlorophenylmagnesium iodide
  • (2-quinaldinate)(carbonyl)(P(4-Cl-C5H4)3)2rhodium(I)

DownStream

  • Oxirane,2,2,3,3-tetramethyl-
  • Pinacolone
  • Phosphine oxide, tris(4-chlorophenyl)- (9CI)
  • 2,2,2-tris(4-chlorophenyl)-4,4,5,5-tetramethyl-1,3,2l5-dioxaphospholane
  • Acetone
  • tris(4-chlorophenyl)-sulfanylidene-λ5-phosphane
  • Phenylisocyanate
  • Phosphonium,tris(4-chlorophenyl)(2-ethoxy-2-oxoethyl)-, bromide (1:1)
  • iridium(3+),1,3,5-trimethylbenzene-6-ide

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • Tris(4-chlorophenyl)phosphine oxide
  • Gold,chloro[tris(4-chlorophenyl)phosphine]
  • Mercury(2+),bis[tris(4-chlorophenyl)phosphine]-,diperchlorate
  • Mercury,dichlorobis[tris(4-chlorophenyl)phosphine]-, (T-4)- (9CI)
  • tris(4-chlorophenyl)-sulfanylidene-λ5-phosphane
  • tris(4-chlorophenyl)gallane