Platinate(1-),trichloro(h2-ethene)-, potassium (1:1)

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Names

[ CAS No. ]:
12012-50-9

[ Name ]:
Platinate(1-),trichloro(h2-ethene)-, potassium (1:1)

[Synonym ]:
Platinate(1-),trichloroethylene-,dipotassium
Platinate(1-),trichloro(ethylene)-,potassium
potassium trichloro(ethene)platinate(II)
Potassium trichloroethyleneplatinate
Potassium trichloro(ethylene)platinate(II)
Platinate(1-),trichloro(eta2-ethene)-,potassium
Potassium ethylenetrichloroplatinate(II)
Pt-93
Zeise-salt
EINECS 234-577-7

Chemical & Physical Properties

[ Molecular Formula ]:
C2H6Cl3K3OPt

[ Molecular Weight ]:
464.80000

[ Exact Mass ]:
462.80400

[ PSA ]:
9.23000

[ LogP ]:
2.92330

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TP1880000
CHEMICAL NAME :
Platinate(1-), trichloroethylene-, dipotassium
CAS REGISTRY NUMBER :
12012-50-9
LAST UPDATED :
199712
DATA ITEMS CITED :
21
MOLECULAR FORMULA :
C2-H4-Cl3-Pt.K
MOLECULAR WEIGHT :
368.60
WISWESSER LINE NOTATION :
G-PT-GG1U1 &-KA- 2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
85 mg/kg
TOXIC EFFECTS :
Tumorigenic - active as anti-cancer agent
REFERENCE :
VOONAW Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1928-37; V.1- 1955- Volume(issue)/page/year: 25(11),47,1979 *** REVIEWS *** ACGIH TLV-TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,213,1971 OSHA PEL (Gen Indu):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.002 mg(Pt)/m3 (dust) JAN 1993 OEL-AUSTRALIA:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-BELGIUM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-DENMARK:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-FINLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-GERMANY:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-HUNGARY:STEL 0.002 mg(Pt)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

Safety Information

[ Risk Phrases ]:
36/37/38

Synthetic Route

Precursor & DownStream

Precursor

  • Potassium tetrachloroplatinate(II)
  • ethene
  • 2,2,2-trichloroethylene platinum(II)

DownStream

  • Platinum,(benzenamine)dichloro(h2-ethene)-, stereoisomer (9CI)
  • Iodo(trimethyl)platinum
  • Platinum, dichloro(h2-ethene)(2,4,6-trimethylpyridine)-,stereoisomer (9CI)
  • platinum

Related Compounds

  • 4-difluoromethoxy-2-methyl-2,3-dihydro-1H-indole
  • Ethyl (4-morpholin-4-yl-6-oxo-1-phenyl-1,6-dihydropyrimidin-2-yl)acetate
  • 1H-Indole, 4-(difluoromethoxy)-2,3-dihydro-
  • 4-(4-methanesulfonylpiperazin-1-ylmethyl)-2,3-dihydro-1H-indole
  • 4-(4-methylpiperazin-1-ylmethyl)-2,3-dihydro-1H-indole
  • (4-Chloro-5-fluoro-6-methoxypyrimidin-2-yl)acetic acid methyl ester
  • 2'-Acetyl-4-[(4-methoxyphenyl)methoxy]-5',6-dimethyl[1(2H),4'-bipyridin]-2-one
  • tert-butyl (1R,5R)-1-(3-methyl-1,2,4-oxadiazol-5-yl)-3-azabicyclo[3.1.0]hexane-3-carboxylate
  • 2-(Oxan-3-yl)propanal
  • 3-iodo-4-nitro-1-(pyridin-3-ylmethyl)-1H-indazole
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