Phenoxyethanol

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Names

[ CAS No. ]:
122-99-6

[ Name ]:
Phenoxyethanol

[Synonym ]:
Phenoxytol
MFCD00046644
Ethylene glycol monophenyl ether
PHENOXETOL
PHENOXYETHYL ALCOHOL
Phenylglycol
emery6705
Dowanol EP
2-hydroxyethyl phenyl ether
dowanoleph
phenoxy ethanol
2-Phenoxyethanol
2-phenyloxyethanol
EINECS 204-589-7
2-phenoxyethan-1-ol
Arosol
Phenyl cellosolve
Rose ether
Ethylene glycol monophenyl ether,PHE-G,PHE-S
Ethanol, 2-phenoxy-
1-Hydroxy-2-phenoxyethane
2-Phenoxy-ethanol

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
245.2±0.0 °C at 760 mmHg

[ Melting Point ]:
11-13 °C

[ Molecular Formula ]:
C8H10O2

[ Molecular Weight ]:
138.164

[ Flash Point ]:
105.3±14.1 °C

[ Exact Mass ]:
138.068085

[ PSA ]:
29.46000

[ LogP ]:
1.16

[ Vapour density ]:
4.8 (vs air)

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.526

[ Storage condition ]:
room temp

[ Water Solubility ]:
30 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KM0350000
CHEMICAL NAME :
Ethanol, 2-phenoxy-
CAS REGISTRY NUMBER :
122-99-6
BEILSTEIN REFERENCE NO. :
1364011
LAST UPDATED :
199710
DATA ITEMS CITED :
22
MOLECULAR FORMULA :
C8-H10-O2
MOLECULAR WEIGHT :
138.18
WISWESSER LINE NOTATION :
Q2OR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1260 mg/kg
TOXIC EFFECTS :
Behavioral - general anesthetic Gastrointestinal - other changes Kidney, Ureter, Bladder - other changes
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
14422 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - acute pulmonary edema
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
554 mg/kg
TOXIC EFFECTS :
Brain and Coverings - other degenerative changes
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
933 mg/kg
TOXIC EFFECTS :
Brain and Coverings - other degenerative changes
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
490 mg/kg
TOXIC EFFECTS :
Brain and Coverings - other degenerative changes
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
5 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
182 gm/kg/13W-I
TOXIC EFFECTS :
Kidney, Ureter, Bladder - changes in bladder weight Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
17500 mg/kg/14D-I
TOXIC EFFECTS :
Gastrointestinal - alteration in gastric secretion Blood - other changes Related to Chronic Data - death
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
15 mg/m3/9W-I
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Behavioral - somnolence (general depressed activity) Liver - liver function tests impaired
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
3 gm/kg/10D-I
TOXIC EFFECTS :
Behavioral - general anesthetic Kidney, Ureter, Bladder - other changes in urine composition Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
14 gm/kg/14D-I
TOXIC EFFECTS :
Blood - other changes Related to Chronic Data - death

MUTATION DATA

TYPE OF TEST :
Mutation test systems - not otherwise specified
TEST SYSTEM :
Bacteria - Escherichia coli
DOSE/DURATION :
2000 ppm
REFERENCE :
MCBIA7 Microbios. (Faculty Press, 88 Regent St., Cambridge, UK) V.1- 1969- Volume(issue)/page/year: 28,7,1980 *** REVIEWS *** TOXICOLOGY REVIEW FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 13,747,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83449 No. of Facilities: 711 (estimated) No. of Industries: 18 No. of Occupations: 19 No. of Employees: 9560 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83449 No. of Facilities: 5523 (estimated) No. of Industries: 63 No. of Occupations: 77 No. of Employees: 111040 (estimated) No. of Female Employees: 46637 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H319

[ Precautionary Statements ]:
P301 + P312 + P330-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R36

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
1

[ RTECS ]:
KM0350000

[ HS Code ]:
29094990

Synthetic Route

Precursor & DownStream

Precursor

  • Phenoxyacetic acid
  • Ethyl phenoxyacetate
  • 2-Chloroethanol
  • Phenol
  • Ethylene carbonate
  • 2-Bromoethanol
  • Benzene, (2-methoxyethoxy)-
  • Methyl 2-phenoxyacetate
  • S-ethyl 2-phenoxyethanethioate

DownStream

  • Natriumphenoxyacetat
  • Sodium benzenolate
  • 2-(4-Bromophenoxy)ethanol
  • Ethanol, 2-(2-bromophenoxy)-
  • 1,4-Benzodioxan
  • 3,4-ethylenedioxyiodobenzene
  • 2-(4-iodo-phenoxy)-ethanol
  • 2-Phenoxyethyl chloroformate
  • Ethanol, 2-phenoxy-,1,1'-carbonate
  • N-methyl-2-phenoxyethanamine

Customs

[ HS Code ]: 2909499000

[ Summary ]:
2909499000. ether-alcohols and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%

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Related Compounds

  • phenoxyethanol
  • 1-phenoxyethanol
  • 2-phenoxyethanol
  • Phenoxyethanol-d2
  • Phenoxyethanol-d4
  • 2-methylphenoxyethanol
  • 4-[(1-Aminocyclopropyl)methyl]-2,6-dimethoxyphenol
  • 6-Bromo-1,3-dichloro-5-fluoro-7-iodoisoquinoline
  • 3-Bromo-2-fluoro-4-iodo-5-methylbenzenamine
  • 3-(5-Bromo-2-nitrophenoxy)propanoic acid
  • Methyl 2-acetyl-5-bromo-4-chlorobenzoate
  • 2-(2-Methoxy-5-(trifluoromethyl)pyridin-4-yl)propanoic acid
  • 3-Bromo-4-[3-(piperidine-1-carbonyl)piperidin-1-yl]pyridine
  • 1-(2-Ethyl-4-(trifluoromethoxy)phenyl)hydrazine
  • 1-Chloro-1-(2,6-diethoxyphenyl)propan-2-one
  • 1-(4-Ethyl-2-(methylthio)phenyl)propan-1-one
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