Pamoic acid

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Names

[ CAS No. ]:
130-85-8

[ Name ]:
Pamoic acid

[Synonym ]:
Pamoic
1,1'-Methylene-bis(2-hydroxy-3-naphthoic acid)
2-Naphthalenecarboxylic acid, 4,4'-methylenebis[3-hydroxy-
4,4-Methylenebis(3-Hydroxy-2-Naphthoic Acid)
EMBIONIC ACID
PAMOIC ACID FREE ACID
2,2'-Dihydroxy-1,1'-dinaphthylmethane-3,3'-dicarboxylic Acid
4,4'-Methylenebis(3-hydroxy-2-naphthoic acid)
Pamoic acid
PAMOIC ACID pure
Embonic acid
4,4'-Methylenedi(3-hydroxy-2-naphthoic Acid)
EINECS 204-998-0
MFCD00004079

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
642.7±55.0 °C at 760 mmHg

[ Melting Point ]:
≥300 °C (dec.)

[ Molecular Formula ]:
C23H16O6

[ Molecular Weight ]:
388.38

[ Flash Point ]:
356.5±28.0 °C

[ Exact Mass ]:
388.094696

[ PSA ]:
115.06000

[ LogP ]:
6.35

[ Vapour Pressure ]:
0.0±2.0 mmHg at 25°C

[ Index of Refraction ]:
1.782

[ Water Solubility ]:
PRACTICALLY INSOLUBLE

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QL2180000
CHEMICAL NAME :
2-Naphthoic acid, 4,4'-methylenebis(3-hydroxy-
CAS REGISTRY NUMBER :
130-85-8
BEILSTEIN REFERENCE NO. :
0901319
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C23-H16-O6
MOLECULAR WEIGHT :
388.39
WISWESSER LINE NOTATION :
L66J CQ DVQ B1- BL66J CQ DVQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 20,573,1982
TYPE OF TEST :
Rinsed with water
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 20,573,1982 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
390 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique. (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France) V.9- 1974- Volume(issue)/page/year: 13,381,1978

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
QL2180000

[ HS Code ]:
2917399090

Synthetic Route

Precursor & DownStream

Precursor

  • Formaldehyde
  • 3-Hydroxy-2-naphthoic acid
  • acetic acid

DownStream

  • Pamoic acid disodium
  • Imipramine pamoate
  • methyl 3-methoxy-4-[(2-methoxy-3-methoxycarbonylnaphthalen-1-yl)methyl]naphthalene-2-carboxylate

Customs

[ HS Code ]: 2918290000

[ Summary ]:
HS: 2918290000 other carboxylic acids with phenol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) VAT:17.0% MFN tariff:6.5% General tariff:30.0%

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