1,3-dithian-2-yl(trimethyl)silane

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Names

[ CAS No. ]:
13411-42-2

[ Name ]:
1,3-dithian-2-yl(trimethyl)silane

[Synonym ]:
1,3-Dithian-2-yltrimethylsilane
(1,3-Dithian-2-yl)trimethylsilane
2-Trimethylsilyl-1,3-dithiane
1,3-dithian-2-yl(trimethyl)silane
Silane, 1,3-dithian-2-yltrimethyl-
EINECS 236-504-4
MFCD00006655

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
261.7±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H16S2Si

[ Molecular Weight ]:
192.417

[ Flash Point ]:
96.1±0.0 °C

[ Exact Mass ]:
192.046265

[ PSA ]:
50.60000

[ LogP ]:
2.65

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.513

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
3334

[ WGK Germany ]:
3

[ HS Code ]:
2934999090

Synthetic Route

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Multicomponent linchpin couplings. Reaction of dithiane anions with terminal epoxides, epichlorohydrin, and vinyl epoxides: efficient, rapid, and stereocontrolled assembly of advanced fragments for complex molecule synthesis.

J. Am. Chem. Soc. 125 , 14435, (2003)

The development, application, and advantages of a one-flask multicomponent dithiane linchpin coupling protocol, over the more conventional stepwise addition of dithiane anions to electrophiles leading...

Lewis base catalyzed 1,3-dithiane addition to carbonyl and imino compounds using 2-trimethylsilyl-1,3-dithiane.

Chem. Asian J. 3(8-9) , 1592-600, (2008)

Lewis base-catalyzed 1,3-dithiane addition to electrophiles such as carbonyl compounds and N-substituted aldimines with 2-trimethylsilyl-1,3-dithiane (TMS-dithiane) is described. By the activation of ...

Smith, A. B., III; Boldi, A. M.

J. Am. Chem. Soc. 119 , 6925, (1997)


More Articles


Related Compounds

  • 1,3-dithian-2-yl(trimethyl)stannane
  • tert-butyl-dimethyl-(2-methyl-1,3-dithian-2-yl)silane
  • tert-butyldimethyl(2-(4-((trimethylsilyl)oxy)butyl)-1,3-dithian-2-yl)silane
  • 1,3-dithian-2-yl-tri(propan-2-yl)silane
  • 1,3-dithian-2-yl(triphenyl)phosphanium,chloride
  • 1,3-dithian-2-yl tetrafluoroborate
  • tert-butyl N-(4-fluoro-2-methyl-1-oxobutan-2-yl)-N-methylcarbamate
  • rac-[(1R,3R)-3-(1,3-benzothiazol-2-yl)-2,2-dimethylcyclopropyl]methanamine
  • methyl (3S)-3-(2-chloro-5-fluorophenyl)-3-hydroxypropanoate
  • 2-Amino-3-(2,5-difluoro-4-methylphenyl)propan-1-ol
  • 2-(2-Fluoro-4-methoxyphenyl)-2-methoxypropan-1-amine
  • 3,3-Difluoro-3-[3-fluoro-4-(trifluoromethyl)phenyl]propan-1-ol
  • 1-(4-Ethoxy-3-methoxyphenyl)-3,3-difluorocyclobutan-1-amine
  • 3-(4-Fluoro-3-methylphenyl)-2-hydroxy-2-methylpropanoic acid
  • 4-{6-Methylimidazo[2,1-b][1,3]thiazol-5-yl}butan-2-amine
  • 1-Methyl-2-(3-nitropropyl)pyrrolidine
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