Aminomalonamid

Suppliers

Names

[ Name ]:
Aminomalonamid

[Synonym ]:
Diethyl aminomalonate hydrochloride
EINECS 236-556-8
Aminomalonic Acid Diethyl Ester Hydrochloride
Propanedioic acid, 2-amino-, diethyl ester, hydrochloride (1:1)
Diethyl aminomalonate hydrochloride (1:1)
diethyl aminopropanedioate hydrochloride (1:1)
Diethyl 2-aminomalonate hydrochloride
MFCD00012510
Aminomalonamid
Propanedioic acid, 2-amino-, 1,3-diethyl ester, hydrochloride (1:1)

Chemical & Physical Properties

[ Density]:
1.129 g/cm3

[ Boiling Point ]:
156 - 158ºC

[ Melting Point ]:
165-170 °C (dec.)(lit.)

[ Molecular Formula ]:
C₇H₁₄ClNO₄

[ Molecular Weight ]:
211.643

[ Flash Point ]:
52.3ºC

[ Exact Mass ]:
211.061142

[ PSA ]:
78.62000

[ LogP ]:
0.94220

[ Vapour Pressure ]:
0.332mmHg at 25°C

[ Storage condition ]:
2~8℃

[ Water Solubility ]:
soluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2922499990

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

ethyl 3-amino-5-benzyl-1H-pyrrole-2-carboxylate
Ethyl 2,4-dimethyl-5-(ethoxycarbonyl)-3-pyrrolepropionate
2-tert-Butoxycarbonylamino-3-oxo-3-phenyl-propionic acid ethyl ester
6-amino-1,4,8,11-tetrazacyclotetradecane-5,7-dione
Propanedioic acid,2-[[(methylamino)carbonyl]amino]-, 1,3-diethyl ester
Propanedioic acid, (1-oxopropyl)-, diethyl ester (9CI)
diethyl 2-(ethylcarbamoylamino)propanedioate
dimethyl 3-amino-1H-pyrrole-2,4-dicarboxylate
ethyl 3-amino-5-phenyl-1H-pyrrole-2-carboxylate
1H-Pyrrole-2-carboxylicacid,3-amino-5-(1,1-dimethylethyl)-,ethylester(9CI)

Customs

[ HS Code ]: 2922499990

[ Summary ]:
HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

Articles

A heterocycle-forming double michael reaction. [5 + 1] annulation route to highly substituted and functionalized piperidines.

Org. Lett. 3(18) , 2911-4, (2001)

[reaction: see text]. Nitrogen-containing tethered diacids, easily prepared by reductive alkylation of diethyl aminomalonate or ethyl cyanoglycinate, undergo double Michael reactions with 3-butyn-2-on...

Reaction control in the organocatalytic asymmetric one-pot, three-component reaction of aldehydes, diethyl alpha-aminomalonate and nitroalkenes: toward diversity-oriented synthesis.

Chemistry 14(32) , 9873-7, (2008)

Spectroscopic studies of quinonoid species from pyridoxal 5'-phosphate.

Biochemistry 27(13) , 4923-33, (1988)

To establish the state of protonation of quinonoid species formed nonenzymically from pyridoxal phosphate (PLP) and diethyl aminomalonate, we have studied absorption spectra of the rapidly established...

Aminomalonamid
Aminomalonamid
Aminomalonamidamidine
(2R)-2-[2-cyclobutyl-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanamido]butanoic acid
(2R)-2-{[(1RS,2SR)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclopentyl]formamido}-4-methylpentanoic acid
4-[(2S)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanoyl]thiomorpholine-2-carboxylic acid
2-Amino-1-(5-fluoro-2-methoxyphenyl)ethanone Hydrochloride
6-(2-{[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)ethyl]sulfanyl}acetamido)-4-methylhexanoic acid
2-[2-(2-{[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)ethyl]sulfanyl}acetamido)phenyl]acetic acid
rac-1-[(1R,2S)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cycloheptaneamido]cyclobutane-1-carboxylic acid
(2R)-1-{1-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclopropanecarbonyl}piperidine-2-carboxylic acid
2-(2-{2-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)ethoxy]acetamido}ethoxy)acetic acid
4-[(2S)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pentanoyl]morpholine-2-carboxylic acid

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