Aminomalonamid
Suppliers
Names
[ CAS No. ]:
13433-00-6
[ Name ]:
Aminomalonamid
[Synonym ]:
Diethyl aminomalonate hydrochloride
EINECS 236-556-8
Aminomalonic Acid Diethyl Ester Hydrochloride
Propanedioic acid, 2-amino-, diethyl ester, hydrochloride (1:1)
Diethyl aminomalonate hydrochloride (1:1)
diethyl aminopropanedioate hydrochloride (1:1)
Diethyl 2-aminomalonate hydrochloride
MFCD00012510
Aminomalonamid
Propanedioic acid, 2-amino-, 1,3-diethyl ester, hydrochloride (1:1)
Chemical & Physical Properties
[ Density]:
1.129 g/cm3
[ Boiling Point ]:
156 - 158ºC
[ Melting Point ]:
165-170 °C (dec.)(lit.)
[ Molecular Formula ]:
C7H14ClNO4
[ Molecular Weight ]:
211.643
[ Flash Point ]:
52.3ºC
[ Exact Mass ]:
211.061142
[ PSA ]:
78.62000
[ LogP ]:
0.94220
[ Vapour Pressure ]:
0.332mmHg at 25°C
[ Storage condition ]:
2~8℃
[ Water Solubility ]:
soluble
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2922499990
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2922499990
[ Summary ]:
HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%
Articles
Org. Lett. 3(18) , 2911-4, (2001)
[reaction: see text]. Nitrogen-containing tethered diacids, easily prepared by reductive alkylation of diethyl aminomalonate or ethyl cyanoglycinate, undergo double Michael reactions with 3-butyn-2-on...
Chemistry 14(32) , 9873-7, (2008)
Biochemistry 27(13) , 4923-33, (1988)
To establish the state of protonation of quinonoid species formed nonenzymically from pyridoxal phosphate (PLP) and diethyl aminomalonate, we have studied absorption spectra of the rapidly established...