Aminomalonamid
Aminomalonamid structure
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Common Name | Aminomalonamid | ||
|---|---|---|---|---|
| CAS Number | 13433-00-6 | Molecular Weight | 211.643 | |
| Density | 1.129 g/cm3 | Boiling Point | 156 - 158ºC | |
| Molecular Formula | C7H14ClNO4 | Melting Point | 165-170 °C (dec.)(lit.) | |
| MSDS | Chinese USA | Flash Point | 52.3ºC | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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A heterocycle-forming double michael reaction. [5 + 1] annulation route to highly substituted and functionalized piperidines.
Org. Lett. 3(18) , 2911-4, (2001) [reaction: see text]. Nitrogen-containing tethered diacids, easily prepared by reductive alkylation of diethyl aminomalonate or ethyl cyanoglycinate, undergo double Michael reactions with 3-butyn-2-one to give highly functionalized and substituted piperidines... |
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Reaction control in the organocatalytic asymmetric one-pot, three-component reaction of aldehydes, diethyl alpha-aminomalonate and nitroalkenes: toward diversity-oriented synthesis.
Chemistry 14(32) , 9873-7, (2008)
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Spectroscopic studies of quinonoid species from pyridoxal 5'-phosphate.
Biochemistry 27(13) , 4923-33, (1988) To establish the state of protonation of quinonoid species formed nonenzymically from pyridoxal phosphate (PLP) and diethyl aminomalonate, we have studied absorption spectra of the rapidly established steady-state mixture of species. We have evaluated the for... |
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Regiochemistry in 1,3-dipolar cycloadditions of the azomethine ylide formed from diethyl aminomalonate and paraformaldehyde.
J. Org. Chem. 67(1) , 298-300, (2002) The azomethine ylide derived from the condensation of diethyl aminomalonate with paraformaldehyde undergoes 1,3-dipolar cycloadditions with acrylate and propiolate derivatives. Contrary to a previous report, these reactions yield mixtures of regioisomers gene... |