(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
Suppliers
Names
[ CAS No. ]:
135616-40-9
[ Name ]:
(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
[Synonym ]:
MFCD00191800
(R,R)-(-)-N,N‘-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
Phenol, 2,2'-[(1R,2R)-1,2-cyclohexanediylbis[nitrilo(E)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)-
2,2'-{(1R,2R)-Cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol)
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
(R,R)-Jacobsen's Ligand
(R,R)-(-)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
(1R,2R)-N,N′-bis-[3,5-di-tert-butyl-salicylidene]-1,2-cyclohexanediamine
2,2'-{(1R,2R)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol]
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
615.2±55.0 °C at 760 mmHg
[ Melting Point ]:
205-207ºC
[ Molecular Formula ]:
C36H54N2O2
[ Molecular Weight ]:
546.826
[ Flash Point ]:
421.6±20.8 °C
[ Exact Mass ]:
546.418518
[ PSA ]:
65.18000
[ LogP ]:
11.18
[ Vapour Pressure ]:
0.0±1.8 mmHg at 25°C
[ Index of Refraction ]:
1.536
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
J. Am. Chem. Soc. 113 , 7063, (1991)
L. Deng, E.N. Jacobsen
J. Org. Chem. 57 , 4320, (1992)
J. Am. Chem. Soc. 113 , 7063, (1991)