Imidacloprid

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Names

[ CAS No. ]:
138261-41-3

[ Name ]:
Imidacloprid

[Synonym ]:
1-((6-chloropyridin-3-yl)methyl)-3-nitroimidazolidin-2-imine
MFCD01721131
EINECS 200-835-2
Imidacloprid
1-((6-Chloro-3-pyridinyl)methyl)-N-nitro-imidazolidinimine

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
442.3±55.0 °C at 760 mmHg

[ Melting Point ]:
144ºC

[ Molecular Formula ]:
C9H10ClN5O2

[ Molecular Weight ]:
255.661

[ Flash Point ]:
221.3±31.5 °C

[ Exact Mass ]:
255.052307

[ PSA ]:
89.04000

[ LogP ]:
-0.43

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.706

[ Storage condition ]:
0-6°C

[ Water Solubility ]:
0.061 g/100mL at 20 ºC

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
NJ0560000
CHEMICAL NAME :
2-Imidazolidinimine, 1-((6-chloro-3-pyridinyl)methyl)-N-nitro-
CAS REGISTRY NUMBER :
138261-41-3
LAST UPDATED :
199806
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C9-H10-Cl-N5-O2
MOLECULAR WEIGHT :
255.69

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
410 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AGJAEP Agrochemcicals Japan. (Japan Plant Protection Association, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.62- 1993- Volume(issue)/page/year: (63),15,1993
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>5323 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AGJAEP Agrochemcicals Japan. (Japan Plant Protection Association, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.62- 1993- Volume(issue)/page/year: (63),15,1993
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AGJAEP Agrochemcicals Japan. (Japan Plant Protection Association, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.62- 1993- Volume(issue)/page/year: (63),15,1993
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
98 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 19,S209,1994 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4550 mg/kg/13W-C
TOXIC EFFECTS :
Behavioral - food intake (animal) Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
TOXID9 Toxicologist. (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway, Akron, OH 44311) V.1- 1981- Volume(issue)/page/year: 36(1,pt2),64,1997

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302-H312-H319-H332

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
N: Dangerous for the environment;Xn: Harmful;F: Flammable;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
26-36-22

[ RIDADR ]:
UN 2588

[ RTECS ]:
NJ0560000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2933399026

Customs

[ HS Code ]: 2933399026

Articles

Efficient removal of insecticide "imidacloprid" from water by electrochemical advanced oxidation processes.

Environ. Sci. Pollut. Res. Int. 21(14) , 8387-97, (2014)

The oxidative degradation of imidacloprid (ICP) has been carried out by electrochemical advanced oxidation processes (EAOPs), anodic oxidation, and electro-Fenton, in which hydroxyl radicals are gener...

Evaluation of imidacloprid-induced neurotoxicity in male rats: a protective effect of curcumin.

Neurochem. Int. 78 , 122-9, (2014)

The present study was carried out to evaluate the neurotoxic effect and biochemical alteration as a result of imidacloprid (IMI) exposure and potential protective role of curcumin (Cur) against it in ...

Capillary electrophoresis-mass spectrometry as a new approach to analyze neonicotinoid insecticides.

J. Chromatogr. A. 1359 , 317-24, (2014)

This paper represents the first report of a capillary electrophoresis (CE) method compatible with mass spectrometry (MS) detection for simultaneously analyzing seven neonicotinoid insecticides (acetam...


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Related Compounds

  • Imidacloprid
  • Imidacloprid-d4
  • Imidacloprid-urea
  • Imidacloprid-olefin
  • N-methylimidacloprid
  • DESNITROIMIDACLOPRID
  • 2-Methyl-1-{4-[(methylamino)methyl]-1,3-thiazol-2-yl}butan-1-one
  • 1-[5-(Hydroxymethyl)-4-methyl-1,3-thiazol-2-yl]ethan-1-one
  • 1-(5-Amino-4-ethyl-1,3-thiazol-2-yl)-2-methylpropan-1-ol
  • 1-(5-Amino-4-ethyl-1,3-thiazol-2-yl)butan-1-ol
  • (5-Amino-4-ethyl-1,3-thiazol-2-yl)(1-methylcyclopropyl)methanol
  • 2-(2,2-Dimethylcyclopropyl)-6-ethylthieno[2,3-d]pyrimidine-4-carboxylic acid
  • 7'-Bromo-1',2'-dihydrospiro[cyclopropane-1,3'-indole]-3-amine
  • 4-Methyl-2-(propan-2-yloxy)hexan-1-amine
  • 2-(5-Chloropyridin-3-yl)-2-methoxyethan-1-amine
  • 2-(5-Ethyl-1,3-thiazol-2-yl)-2-methoxyethan-1-amine
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