1-Boc-4-(2-oxo-ethyl)piperidine

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Names

[ CAS No. ]:
142374-19-4

[ Name ]:
1-Boc-4-(2-oxo-ethyl)piperidine

[Synonym ]:
1-Boc-4-(2-oxo-ethyl)piperidine
1-Piperidinecarboxylic acid, 4-(2-oxoethyl)-, 1,1-dimethylethyl ester
4-(2-Oxoethyl)piperidine-1-carboxylic Acid tert-Butyl Ester
tert-Butyl 4-(2-oxoethyl)piperidine-1-carboxylate
2-Methyl-2-propanyl 4-(2-oxoethyl)-1-piperidinecarboxylate
2-(N-BOC-4-piperidinyl)acetaldehyde

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
318.1±15.0 °C at 760 mmHg

[ Melting Point ]:
38-42ºC

[ Molecular Formula ]:
C12H21NO3

[ Molecular Weight ]:
227.300

[ Flash Point ]:
146.2±20.4 °C

[ Exact Mass ]:
227.152145

[ PSA ]:
46.61000

[ LogP ]:
1.45

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.467

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Boc-4-(2-hydroxyethyl)piperidine
  • Oxalyl chloride
  • N-Boc-4-ethyl piperidinecarboxylate
  • tert-butyl 4-(2-oxoethylidene)piperidine-1-carboxylate
  • 2-(4-Piperidinyl)ethanol
  • 4-Pyridinylacetic acid
  • 4-(2-Ethoxy-2-oxoethylidene)-1-piperidinecarboxylic acid tert-butyl ester
  • Di-tert-butyl dicarbonate
  • 4-(Carboxymethyl)pyridinium chloride
  • 1-Boc-4-piperidylacetic acid

DownStream

  • 1-BOC-4-(4-METHOXY-4-OXO-2-BUTENYL)PIPERIDINE
  • tert-butyl 4-(1-bromo-2-oxoethyl)piperidine-1-carboxylate
  • tert-Butyl 4-(2-(methylamino)ethyl)piperidine-1-carboxylate
  • 1-N-Boc-4-(3-Cbz-amino-3-methoxycarbonylallyl)piperidine
  • tert-butyl 4-(3-hydroxyprop-1-en-2-yl)piperidine-1-carboxylate
  • 1-Boc-4-(4-Bromobutyl)piperidine
  • 4-(1-Boc-4-piperidyl)-1-butanol
  • N-Boc-4-Piperidin-4-yl-butyric acid
  • 1-BOC-4-(CYANOMETHYL)PIPERIDINE
  • tert-Butyl 4-(prop-2-yn-1-yl)piperidine-1-carboxylate

Articles

Enantioselective organo-SOMO catalysis: the alpha-vinylation of aldehydes.

J. Am. Chem. Soc. 130 , 398, (2008)

Tetrahedron Lett. 47 , 2515, (2006)


More Articles

Related Compounds

  • 1-BOC-4-(2-METHANESULFONYLOXY-ETHYL)-PIPERIDINE
  • 1-Boc-4-(2-oxo-piperidin-1-ylmethyl)piperidine
  • 1-BOC-4-(2-OXO-3-PYRIDIN-4-YL-PROPYL)-PIPERIDINE
  • 1-BOC-4-(2-CBZ-AMINO-2-METHOXYCARBONYL-ETHYL)PIPERIDINE
  • (R)-1-Boc-2-(2-Oxoethyl)Piperidine
  • (S)-1-Boc-2-(2-Oxoethyl)Piperidine
  • 2-(Isopropylthio)-6-oxo-1,6-dihydropyrimidine-5-carboxylic acid
  • 3-Hydroxy-2-oxopentanal
  • 2-Cyclopropyl-4-morpholinopyrimidine-5-carboxylic acid
  • 6-(4-Pyridinyl)-5-hexyn-1-ol
  • 1-(3,5-Dichlorophenyl)-5-hydroxy-1h-pyrazole-3-carboxylic acid
  • 2-(Methoxymethyl)-7-methyl-[1,2,4]triazolo[1,5-a]pyrimidine-6-carboxylic acid
  • 2-amino-4-(methylthio)-7,8-dihydroquinazolin-5(6H)-one
  • 1,4-Dihydro-6-(2-methylphenyl)-1,2,4,5-tetrazin-3-amine
  • 1,2,4-Triazolo[4,3-a]pyrimidine-3-carboxylic acid, 7-phenyl-
  • 1-[2-(Cyclohex-1-EN-1-YL)ethyl]-5-oxopyrrolidine-3-carboxylic acid
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