Gold(1+) chloride-triphenylphosphine (1:1:1)

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Names

[ CAS No. ]:
14243-64-2

[ Name ]:
Gold(1+) chloride-triphenylphosphine (1:1:1)

[Synonym ]:
Phosphine, triphenyl-, gold(1+) salt, hydrochloride (1:1:1)
Gold(1+) chloride - triphenylphosphine (1:1:1)
(Triphenylphosphine)gold(I) Chloride
EINECS 238-117-6
Chloro(triphenylphosphine)gold
(Ph3P)AuCl (Triphenylphosphinegold(I) chloride
MFCD00009588
chlorogold,triphenylphosphane

Chemical & Physical Properties

[ Boiling Point ]:
360ºC at 760 mmHg

[ Melting Point ]:
248-249°C

[ Molecular Formula ]:
C18H15AuClP

[ Molecular Weight ]:
494.71

[ Flash Point ]:
181.7ºC

[ Exact Mass ]:
494.026489

[ PSA ]:
13.59000

[ LogP ]:
4.13180

[ Vapour Pressure ]:
4.74E-05mmHg at 25°C

[ Storage condition ]:
Store under Nitrogen

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37/39-S37/39

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Chloro(tetrahydrothiophene)gold(I)
  • Triphenylphosphine
  • methylimidazole
  • cis-[AuIII(C6F5)Cl2(PPh3)]
  • Gold, [1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN](triphenylphosphine)-
  • Chloro(dimethyl sulfide)gold(I)
  • 2,3,4,5,6-Pentafluorobenzeneboronic acid
  • [AuCl(2,2'-thiodiethanol)]

DownStream

  • gold,2-[4-[2-(4-nitrophenyl)ethynyl]phenyl]ethynyl-triphenylphosphanium
  • Gold, azido(triphenylphosphine)-
  • Dichloro(DPPE)digold(I) ,96
  • Acetyl chloride
  • (4-fluorophenyl)-triphenylphosphanium,gold
  • (1,5-Cyclooctadiene)rhodium chloride dimer
  • gold(1+),triphenylphosphane,perchlorate
  • gold,iodo(triphenyl)phosphanium

Articles

A mass spectrometric investigation of the binding of gold antiarthritic agents and the metabolite [Au(CN)2]- to human serum albumin.

J. Biol. Inorg. Chem. 11(5) , 559-70, (2006)

Electrospray ionisation (ESI) mass spectrometry was used to examine the reactions of the clinically used antiarthritic agent [Au(S2O3)2]3-, and AuPEt3Cl, a derivative of another clinically used agent ...

Development of a gold-multifaceted catalysis approach to the synthesis of highly substituted pyrroles: mechanistic insights via Huisgen cycloaddition studies.

J. Org. Chem. 78(3) , 920-34, (2013)

A novel gold-catalyzed method for the regioselective synthesis of highly substituted pyrroles directly from oximes and alkynes was developed via independent optimization of two key steps of the proces...

A powerful chiral counterion strategy for asymmetric transition metal catalysis.

Science 317 , 496-499, (2007)

Traditionally, transition metal-catalyzed enantioselective transformations rely on chiral ligands tightly bound to the metal to induce asymmetric product distributions. Here we report high enantiosele...


More Articles

Related Compounds

  • Chloro[tri(o-tolyl)phosphine]gold(I)
  • N-[bis(dimethylamino)phosphanyl]-N-methylmethanamine,gold(1+),chloride
  • 2-diphenylphosphanylethyl(diphenyl)phosphane,gold(1+),chloride
  • chlorobis(dicyclohexylphenylphosphine)gold(I)
  • benzylbis(triphenylphosphine)palladium(ii) chloride
  • gold(1+),triphenylphosphane,bromide