(+)-Dehydroabiethylamine

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Names

[ CAS No. ]:
1446-61-3

[ Name ]:
(+)-Dehydroabiethylamine

[Synonym ]:
Leelamine hydrochloride,(1R,4aS,10aR)-1,2,3,4,4a,9,10,10a-Octahydro-1-,4a-dimethyl-7-(1-methylethyl)-1-phenanthrenemethanaminehydrochloride
EINECS 215-899-7
MFCD00213430
(+)-DehydroabietylaMine [Optical Resolving Agent]
Dehydroabiethylamine

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
382.9±11.0 °C at 760 mmHg

[ Melting Point ]:
44.50℃

[ Molecular Formula ]:
C20H31N

[ Molecular Weight ]:
285.467

[ Flash Point ]:
156.7±9.1 °C

[ Exact Mass ]:
285.245636

[ PSA ]:
26.02000

[ LogP ]:
6.40

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.528

[ Storage condition ]:
Desiccate at +4°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TP8701000
CHEMICAL NAME :
Podocarpa-8,11,13-trien-15-amine, 13-isopropyl-
CAS REGISTRY NUMBER :
1446-61-3
BEILSTEIN REFERENCE NO. :
3084620
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C20-H31-N

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
TP8701000

[ HS Code ]:
3806900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Phenanthrenecarbonitrile,1,2,3,4,4a,9,10,10a-octahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aS,10aR)-
  • dehydroabietic acid

DownStream

  • DEHYDROABIETHYL ISOTHIOCYANATE

Customs

[ HS Code ]: 2921499090

[ Summary ]:
2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Synthesis of Tertiary and Quaternary Amine Derivatives from Wood Resin as Chiral NMR Solvating Agents.

Molecules 20 , 20873-86, (2015)

Chiral tertiary and quaternary amine solvating agents for NMR spectroscopy were synthesized from the wood resin derivative (+)-dehydroabietylamine (2). The resolution of enantiomers of model compounds...


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