(-)-MENTHYL CHLOROFORMATE

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Names

[ CAS No. ]:
14602-86-9

[ Name ]:
(-)-MENTHYL CHLOROFORMATE

[Synonym ]:
(-)-Chloroformyloxy-p-menthane
Carbonochloridic acid, (1R,2S,5S)-5-methyl-2-(1-methylethyl)cyclohexyl ester
(1R,2S,5S)-2-Isopropyl-5-methylcyclohexyl carbonochloridate
(-)-MENTHYL CHLOROFORMATE
(1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate
MFCD00009694
(1R)-(-)-Menthyl chloroformate

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
233.9±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C11H19ClO2

[ Molecular Weight ]:
218.720

[ Flash Point ]:
84.1±11.5 °C

[ Exact Mass ]:
218.107361

[ PSA ]:
26.30000

[ LogP ]:
4.83

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.462

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H331

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;N: Dangerous for the environment;

[ Risk Phrases ]:
R23;R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S61

[ RIDADR ]:
UN 3277 6.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Triphosgene
  • L-Menthol
  • phosgene
  • Diphosgene

DownStream

  • L-Menthol
  • [(1R,2S,5R)-5-methyl-2-propan-2-yl-cyclohexyl] N-aminocarbamate

Articles

Design and synthesis of chiral N-chloroimidodicarbonates: application to asymmetric chlorination of silyl enol ethers.

J. Org. Chem. 72 , 4872, (2007)

New chiral N-chloroimidodicarbonates, which function as efficient chiral chlorinating agents, were designed and synthesized. Among these, C(2)-symmetric (1R,2S,5R)-(-)-menthyl-N-chloroimidodicarbonate...

Stereospecific liquid chromatographic analysis of racemic adrenergic drugs utilizing precolumn derivatization with (-)-menthyl chloroformate.

J. Chromatogr. A. 493(2) , 402-8, (1989)

Resolution of antihypertensive aryloxypropanolamine enantiomers by reversed-phase chromatography of (-)-menthyl chloroformate derivatives.

J. Chromatogr. A. 487(1) , 197-203, (1989)


More Articles

Related Compounds

  • (-)-MENTHYLCHLOROFORMATE
  • Chloroformic acid p-menthan-3-yl ester
  • 3-(3-Chloropropyl)-5,5-dimethylimidazolidine-2,4-dione
  • Artonol C
  • N-(4-methoxyphenethyl)-2-((6-(3-methoxyphenyl)-[1,2,4]triazolo[4,3-b]pyridazin-3-yl)thio)acetamide
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 4-(2-(3,4-Dimethylphenyl)acetyl)-3,3-dimethylpiperazin-2-one
  • 4-(2-Aminophenyl)butan-1-ol
  • Methyl 4-[({5-chloro-2-[(4-methylbenzyl)thio]pyrimidin-4-yl}carbonyl)amino]benzoate
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-