(-)-MENTHYL CHLOROFORMATE

Modify Date: 2024-01-05 16:43:22

(-)-MENTHYL CHLOROFORMATE structure	Common Name	(-)-MENTHYL CHLOROFORMATE
	CAS Number	14602-86-9	Molecular Weight	218.720
	Density	1.0±0.1 g/cm3	Boiling Point	233.9±0.0 °C at 760 mmHg
	Molecular Formula	C₁₁H₁₉ClO₂	Melting Point	N/A
	MSDS	Chinese USA	Flash Point	84.1±11.5 °C
	Symbol	GHS05, GHS06	Signal Word	Danger

Name	(-)-Menthyl Chloroformate
Synonym	More Synonyms

Density	1.0±0.1 g/cm3
Boiling Point	233.9±0.0 °C at 760 mmHg
Molecular Formula	C₁₁H₁₉ClO₂
Molecular Weight	218.720
Flash Point	84.1±11.5 °C
Exact Mass	218.107361
PSA	26.30000
LogP	4.83
Vapour Pressure	0.1±0.4 mmHg at 25°C
Index of Refraction	1.462
Storage condition	2-8°C

(-)-MENTHYL CHLOROFORMATE MSDS(Chinese)

Symbol	GHS05, GHS06
Signal Word	Danger
Hazard Statements	H314-H331
Precautionary Statements	P261-P280-P305 + P351 + P338-P310
Personal Protective Equipment	Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	T: Toxic;N: Dangerous for the environment;
Risk Phrases	R23;R34
Safety Phrases	S26-S36/37/39-S45-S61
RIDADR	UN 3277 6.1/PG 2
WGK Germany	3
Packaging Group	II
Hazard Class	6.1

Triphosgene

CAS#:32315-10-9

L-Menthol

CAS#:2216-51-5

~99%

(-)-MENTHYL CHL...

CAS#:14602-86-9

Literature: Shen, Yi; Sun, Yufeng; Sang, Zhipei; Sun, Chengjun; Dai, Ya; Deng, Yong Molecules, 2012 , vol. 17, # 7 p. 8661 - 8673

phosgene

CAS#:75-44-5

L-Menthol

CAS#:2216-51-5

~81%

(-)-MENTHYL CHL...

CAS#:14602-86-9

Literature: Gouverneur; McCarthy; Mineur; Belotti; Dive; Ghosez Tetrahedron, 1998 , vol. 54, # 35 p. 10537 - 10554

L-Menthol

CAS#:2216-51-5

Diphosgene

CAS#:503-38-8

(-)-MENTHYL CHL...

CAS#:14602-86-9

Literature: Journal of the American Chemical Society, , vol. 114, # 1 p. 121 - 125

Precursor 4
CAS#:32315-10-9 Triphosgene CAS#:2216-51-5 L-Menthol CAS#:75-44-5 phosgene CAS#:503-38-8 Diphosgene
DownStream 2
CAS#:2216-51-5 L-Menthol CAS#:21391-40-2 [(1R,2S,5R)-5-m...

Design and synthesis of chiral N-chloroimidodicarbonates: application to asymmetric chlorination of silyl enol ethers.

J. Org. Chem. 72 , 4872, (2007)

New chiral N-chloroimidodicarbonates, which function as efficient chiral chlorinating agents, were designed and synthesized. Among these, C(2)-symmetric (1R,2S,5R)-(-)-menthyl-N-chloroimidodicarbonate...

Stereospecific liquid chromatographic analysis of racemic adrenergic drugs utilizing precolumn derivatization with (-)-menthyl chloroformate.

J. Chromatogr. A. 493(2) , 402-8, (1989)

Resolution of antihypertensive aryloxypropanolamine enantiomers by reversed-phase chromatography of (-)-menthyl chloroformate derivatives.

J. Chromatogr. A. 487(1) , 197-203, (1989)