1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

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Names

[ CAS No. ]:
14647-23-5

[ Name ]:
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

[Synonym ]:
1,2-Bis(Dip
Nickel(2+) chloride ethane-1,2-diylbis(diphenylphosphine) (1:2:1)
Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II)
1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride
[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride
Dichloronickel - ethane-1,2-diylbis(diphenylphosphine) (1:1)
2-diphenylphosphanylethyl(diphenyl)phosphane,nickel(2+),dichloride
1,2-Ethanediylbis(diphenylphosphine) - dichloronickel (1:1)
Nickel(2+) chloride - ethane-1,2-diylbis(diphenylphosphine) (1:2:1)
MFCD00013313
phosphine, 1,1'-(1,2-ethanediyl)bis[1,1-diphenyl-, nickel(2+) salt, hydrochloride (1:1:2)
[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)

Chemical & Physical Properties

[ Boiling Point ]:
514.8ºC at 760mmHg

[ Melting Point ]:
263-265 °C(lit.)

[ Molecular Formula ]:
C26H24Cl2NiP2

[ Molecular Weight ]:
528.016

[ Flash Point ]:
281.7ºC

[ Exact Mass ]:
526.008362

[ PSA ]:
27.18000

[ Vapour Pressure ]:
3.38E-10mmHg at 25°C

[ Storage condition ]:
Refrigerator

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H312-H315-H319-H332-H334-H335-H350

[ Precautionary Statements ]:
P201-P261-P280-P305 + P351 + P338-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic

[ Risk Phrases ]:
R45;R20/21/22;R36/37/38;R40;R42/43

[ Safety Phrases ]:
S53-S22-S26-S36-S45-S52

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • {NiBr2-(1.2-Bis-diphenylphosphino-aethan)2}
  • dibromonickel,2-diphenylphosphaniumylethyl(diphenyl)phosphanium
  • {NiJ2-(1.2-Bis-diphenylphosphino-aethan)2}

DownStream

  • 2-Propyl-6-methoxynaphthalene
  • Bis(cyclopentadienyl)zirconium dichloride
  • dibromonickel,2-diphenylphosphaniumylethyl(diphenyl)phosphanium
  • bis(methylcyclopentadienyl)titanium dichloride
  • Chlorotrimethylsilane

Related Compounds

  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 5-Chloro-1-(4-chlorobenzoyl)-6-methoxy-1H-indole-3-acetic acid
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 5-(Difluoromethyl)-3-nitro-2-(trifluoromethoxy)pyridin-4-amine
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 4-Cyano-2-(difluoromethoxy)-6-(trifluoromethyl)benzoic acid
  • 1-(3-Aminobutyl)naphthalen-2-ol
  • 5-Ethenyl-1-methyl-1h-1,2,3-triazole