Methyl 4-bromo-3-methylbenzoate

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Names

[ CAS No. ]:
148547-19-7

[ Name ]:
Methyl 4-bromo-3-methylbenzoate

[Synonym ]:
Methyl-4-brom-3-methylbenzolcarboxylat
3-Bromo-p-toluic Acid Methyl Ester
4-Bromo-3-methylbenzoic Acid Methyl Ester
Methyl 3-Bromo-p-toluate
3-bromo-4-methyl-benzoic acid methyl ester
Methyl 4-bromo-3-methylbenzoate
Methyl 3-Bromo-4-Methylbenzoate
methyl 3-bromotoluate
METHYL4-BROMO-3-METHYLBENZOATE
4-Bromo-3-methyl-benzoic acid methyl ester
Methyl 4-Bromo-m-toluate
Methyl3-bromo-4-methylbenzoate
Benzoic acid, 4-bromo-3-methyl-, methyl ester
4-Bromo-m-toluic Acid Methyl Ester
methyl 3-methyl-4-bromobenzoate
MFCD00673014
3-Bromo-4-methylbenzoic Acid Methyl Ester

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
287.4±20.0 °C at 760 mmHg

[ Melting Point ]:
38-44 °C(lit.)

[ Molecular Formula ]:
C9H9BrO2

[ Molecular Weight ]:
229.071

[ Flash Point ]:
127.6±21.8 °C

[ Exact Mass ]:
227.978592

[ PSA ]:
26.30000

[ LogP ]:
3.41

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.545

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • 4-Bromo-3-methylbenzoic acid
  • methyl iodide
  • Methyl 4-amino-3-methylbenzoate

DownStream

  • 4-(METHOXYCARBONYL)-2-METHYLPHENYLBORONIC ACID PINACOL ESTER
  • 4-Bromo-3-bromomethyl-benzoic acid methyl ester
  • methyl 4-bromo-3-(dibromomethyl)benzoate
  • 1-bromo-4-(bromomethyl)-2-methylbenzene
  • 4-Bromo-3-methylbenzaldehyde
  • 4-Bromo-3-methylbenzoic acid
  • tert-butyl 4-bromo-3-methylbenzoate
  • Methyl 4-Fluoro-3-methylbenzoate
  • Methyl 4-cyano-3-methylbenzoate

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Synthesis and properties of mesogen-jacketed liquid crystalline polymers with asymmetry mesogenic core. Chen S, et al.

Macromolecules 40(16) , 5718-5725, (2007)


More Articles

Related Compounds

  • METHYL4-BROMO-3-METHYLBENZOATE
  • Methyl4-bromo-3-chloro-5-(trifluoromethoxy)benzoate
  • Butyl 4-bromo-3-methylbenzoate
  • Methyl 4-bromo-3-methylbenzoate
  • cyclopentyl 2-bromo-3-methylbenzoate
  • Methyl 2-bromo-3-methylbenzoate
  • (3-Methylpyrrolidin-2-yl)methanethiol
  • 3-(1,4-dimethyl-1H-pyrazol-3-yl)-2-hydroxy-2-methylpropanoic acid
  • 4-(2-Azidoethyl)-2-bromo-1-methylbenzene
  • 3-Acetamido-4-(propan-2-yl)benzoic acid
  • O-[2-(3-bromo-5-methylthiophen-2-yl)ethyl]hydroxylamine
  • 3-(6-Bromopyridin-3-yl)-3,3-difluoropropan-1-amine
  • 4-Bromo-3-cyclopropyl-1,2-oxazole
  • 4-(Aminomethyl)-4-[5-(trifluoromethyl)thiophen-2-yl]cyclohexan-1-ol
  • 3-(But-3-yn-2-yl)benzene-1,2-diol
  • 5-(2-Methyloxolan-3-yl)-1,2-oxazol-3-amine
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