methyl penta-2,4-dienoate

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Names

[ Name ]:
methyl penta-2,4-dienoate

[Synonym ]:
penta-2,4-dienoic acid methyl ester
2,4-pentadienoic acid methyl ester
methyl 1,3-butadiene-1-carboxylate mixt. of cis/trans
methyl pentadienate
METHYL 1,3-BUTADIENE-1-CARBOXYLATE
Dimethyl-2,4-pentandioate
Penta-2,4-diensaeure-methylester
1-methoxycarbonyl-1,3-butadiene
METHYL 1,3-BUTADIENE-1-CARBOXYLATE MIXT. OF CIS/TRANS,STAB.
METHYL 2,4-PENTADIENOATE
Vynilacrylic acid methyl ester
1-methoxycarbonylbuta-1,3-diene
methyl penta-2,4-dienoate

Chemical & Physical Properties

[ Density]:
0.936g/cm3

[ Boiling Point ]:
135.2ºC at 760mmHg

[ Molecular Formula ]:
C₆H₈O₂

[ Molecular Weight ]:
112.12700

[ Flash Point ]:
46.4ºC

[ Exact Mass ]:
112.05200

[ PSA ]:
26.30000

[ LogP ]:
0.90160

[ Vapour Pressure ]:
7.8mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.484

[ Storage condition ]:
−20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335-H412

[ Precautionary Statements ]:
P261-P273-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
10-36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
UN 3272 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

Synthetic Route

Click to get detail synthetic route

Articles

Aza-Morita-Baylis-Hillman reactions and cyclizations of conjugated dienes activated by sulfone, ester, and keto groups.

J. Org. Chem. 72(9) , 3326-31, (2007)

The aza-Morita-Baylis-Hillman reactions of aldimines 2 with several activated conjugated dienes were found to proceed smoothly in DMF in the presence of 3-hydroxyquinuclidine (HQD). Imines 2 reacted w...

methyl penta-2,4-dienoate
methyl 5-(4-methoxyphenyl)penta-2,4-dienoate
methyl 5-(4-methylphenyl)penta-2,4-dienoate
methyl 5-(3-methoxyphenyl)penta-2,4-dienoate
methyl 5-(4-chlorophenyl)penta-2,4-dienoate
Methyl 5-(2-Anthryl)penta-2,4-dienoate
(9H-fluoren-9-yl)methyl N-{[5-(hydroxymethyl)-1,3,4-thiadiazol-2-yl]methyl}carbamate
(9H-fluoren-9-yl)methyl N-[(3R)-3-hydroxybutyl]-N-methylcarbamate
rac-(9H-fluoren-9-yl)methyl (3aR,6aR)-6a-(hydroxymethyl)-hexahydro-2H-furo[2,3-c]pyrrole-5-carboxylate
(9H-fluoren-9-yl)methyl 3-cyclopropyl-3-(hydroxymethyl)morpholine-4-carboxylate
(9H-fluoren-9-yl)methyl 3-(2-hydroxyethyl)-3-methylpyrrolidine-1-carboxylate
(9H-fluoren-9-yl)methyl 4-(1-hydroxy-2-oxopropyl)piperidine-1-carboxylate
rac-(9H-fluoren-9-yl)methyl N-[(1R,3S,4R)-3-hydroxy-4-methoxycyclopentyl]carbamate
(9H-fluoren-9-yl)methyl 2-(hydroxymethyl)-3,3-dimethylpiperidine-1-carboxylate
(9H-fluoren-9-yl)methyl N-[1-(4-hydroxyoxan-4-yl)ethyl]carbamate
(9H-fluoren-9-yl)methyl (2S)-2-(2-hydroxy-2,3-dihydro-1H-inden-2-yl)pyrrolidine-1-carboxylate

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