methyl penta-2,4-dienoate

methyl penta-2,4-dienoate Structure
methyl penta-2,4-dienoate structure
Common Name methyl penta-2,4-dienoate
CAS Number 1515-75-9 Molecular Weight 112.12700
Density 0.936g/cm3 Boiling Point 135.2ºC at 760mmHg
Molecular Formula C6H8O2 Melting Point N/A
MSDS Chinese USA Flash Point 46.4ºC
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

Aza-Morita-Baylis-Hillman reactions and cyclizations of conjugated dienes activated by sulfone, ester, and keto groups.

J. Org. Chem. 72(9) , 3326-31, (2007)

The aza-Morita-Baylis-Hillman reactions of aldimines 2 with several activated conjugated dienes were found to proceed smoothly in DMF in the presence of 3-hydroxyquinuclidine (HQD). Imines 2 reacted with 1-(p-toluenesulfonyl)-1,3-butadiene (3), methyl 2,4-pen...