(r)-(+)-n-(tert-butoxycarbonyl)-o-

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Names

[ Name ]:
(r)-(+)-n-(tert-butoxycarbonyl)-o-

[Synonym ]:
tert-butyl N-[(1R)-2-(tert-butyldimethylsiloxy)-1-(hydroxymethyl)ethyl]carbamate
N-Boc-serin-(O-t-butyldimethylsilyl)-ol
O-t-butyldimethylsilyl-N-[(1,1-dimethylethoxy)carbonyl]-L-serinol
MFCD03093881
(R)-(+)-N-(tert-Butoxycarbonyl)-O-(tert-butyldimethylsilyl)serinol
(R)-[1-(tert-butyl-dimethyl-silanyloxymethyl)-2-hydroxy-ethyl]-carbamic acid tert-butyl ester
1,1-dimethylethyl [(1R)-2-{[(1,1-dimethylethyl)(dimethyl)silyl]oxy}-1-(hydroxymethyl)ethyl]carbamate
tert-butyl (R)-1-(tert-butyldimethylsilyloxy)-3-hydroxypropan-2-yl carbamate
(R)-tert-butyl 1-(tert-butyldimethylsilyloxy)-3-hydroxypropan-2-ylcarbamate

Chemical & Physical Properties

[ Density]:
0.979g/cm3

[ Boiling Point ]:
377.301ºC at 760 mmHg

[ Melting Point ]:
32-37ºC(lit.)

[ Molecular Formula ]:
C₁₄H₃₁NO₄Si

[ Molecular Weight ]:
305.48600

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
305.20200

[ PSA ]:
71.28000

[ LogP ]:
3.09820

[ Vapour Pressure ]:
0mmHg at 25°C

[ Index of Refraction ]:
1.452

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

O-t-butyldimethylsilyl-N-[(1,1-dimethylethoxy)carbonyl]-N-hydroxymethyl-L-serinol
Di-tert-butyl dicarbonate
(R)-2-amino-3-(tert-butyldimethylsiloxy)propan-1-ol
Boc-Ser-OMe
tert-Butyldimethylsilyl chloride
(4S)-4-[(t-butyldimethylsilyloxy)methyl]-3-[(1,1-dimethylethoxy)carbonyl]-5-oxazolidinone
O-t-butyldimethylsilyl-N-[(1,1-dimethylethoxy)carbonyl]-N-hydroxymethyl-L-serinal hemiacetal

DownStream

Boc-D-Abu-OH
(S)-Garner's Aldehyde
N-Boc-D-leucinol
Boc-D-Phe-OH
N-Boc-D-phenylalaninol
tert-Butyl (1-hydroxybutan-2-yl)carbamate
Boc-D-Leu-OH.H2O
2-Methyl-2-propanyl (3R)-3-formyl-1-oxa-4-azaspiro[4.5]decane-4-c arboxylate

Related Compounds

(R)-(+)-N--2-methyl-3-phenylalanine methyl ester
(R)-2-((tert-butoxycarbonyl)amino)propyl 4-methylbenzenesulfonate
(R)-N-(tert-butoxycarbonyl)-5-formylpyrrolidin-2-one
(R)-N-(tert-butoxycarbonyl)-4-(2',2'-dibromoethenyl)-2,2,4-trimethyl-3-oxazolidine
(R)-N-(tert-butoxycarbonyl)-4-vinyl-2,2,4-trimethyl-3-oxazolidine
(R)-N-(tert-butoxycarbonyl)-4-fluoro-3-nitrophenylalanine methyl ester
Citric Acid (3-Methanethiosulfonate Ethyl Amide)
Diethyl N-(2-Malonyl)-3-(methylsulfonylthio)-propanamide
3,12-Diimino-2,4,11,13-tetraazatetradecanediamide
5-Fluoro SDB-005
tert-Butyl (R)-2-(4-fluorophenyl)piperidine-1-carboxylate
1-[3,5-Bis(trifluoromethyl)phenyl]-2-[[2-(4-fluoro-2-methoxy-5-propan-2-ylphenyl)-5-(trifluoromethyl)phenyl]methylideneamino]propan-1-ol
tert-Butyl (S)-2-(4-fluorophenyl)piperidine-1-carboxylate
Ethyl 6-(cyclopentylmethylene)-5,6,7,8-tetrahydro-5-oxo-2-quinolinecarboxylate
Dihydro-5-[[4-methoxy-3-(phenylmethyl)phenyl]methylene]-1,3-dimethyl-2-thioxo-4,6(1H,5H)-pyrimidinedione
5-(5-chloro-2-difluoromethoxyphenyl)-1-(2-trimethylsilanyl-ethoxymethyl)-1H-pyrazol-4-ylamine

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