(r)-(+)-n-(tert-butoxycarbonyl)-o-
Modify Date: 2024-01-09 18:29:14
(r)-(+)-n-(tert-butoxycarbonyl)-o- structure
|
Common Name | (r)-(+)-n-(tert-butoxycarbonyl)-o- | ||
|---|---|---|---|---|
| CAS Number | 152491-85-5 | Molecular Weight | 305.48600 | |
| Density | 0.979g/cm3 | Boiling Point | 377.301ºC at 760 mmHg | |
| Molecular Formula | C14H31NO4Si | Melting Point | 32-37ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | >230 °F | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | tert-butyl N-[(2R)-1-[tert-butyl(dimethyl)silyl]oxy-3-hydroxypropan-2-yl]carbamate |
|---|---|
| Synonym | More Synonyms |
| Density | 0.979g/cm3 |
|---|---|
| Boiling Point | 377.301ºC at 760 mmHg |
| Melting Point | 32-37ºC(lit.) |
| Molecular Formula | C14H31NO4Si |
| Molecular Weight | 305.48600 |
| Flash Point | >230 °F |
| Exact Mass | 305.20200 |
| PSA | 71.28000 |
| LogP | 3.09820 |
| Vapour Pressure | 0mmHg at 25°C |
| Index of Refraction | 1.452 |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xi: Irritant; |
| Risk Phrases | R36/37/38 |
| Safety Phrases | S26 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
|
~89%
(r)-(+)-n-(tert... CAS#:152491-85-5 |
| Literature: Bhowmik, Subhendu; Batra, Sanjay European Journal of Organic Chemistry, 2013 , # 31 p. 7145 - 7151 |
|
~70%
(r)-(+)-n-(tert... CAS#:152491-85-5 |
| Literature: Yoo, Dongwon; Seok Oh, Joon; Lee, Dong-Whal; Kim, Young Gyu Journal of Organic Chemistry, 2003 , vol. 68, # 7 p. 2979 - 2982 |
|
~91%
(r)-(+)-n-(tert... CAS#:152491-85-5 |
| Literature: Bartoli, Giuseppe; Di Antonio, Giustino; Fiocchi, Roberto; Giuli, Sandra; Marcantoni, Enrico; Marcolini, Mauro Synthesis, 2009 , # 6 art. no. Z24108SS, p. 951 - 956 |
|
~%
(r)-(+)-n-(tert... CAS#:152491-85-5 |
| Literature: Colarusso, Stefania; Conte, Immacolata; Di Filippo, Marcello; Ercolani, Caterina; MacKay, Angela C.; Palumbi, Maria Cecilia; Rico Ferreira, Maria Del Rosario; Stansfield, Ian; Zaramella, Simone; Narjes, Frank; Habermann, Joerg Synlett, 2011 , # 11 p. 1527 - 1532 |
|
~%
(r)-(+)-n-(tert... CAS#:152491-85-5 |
| Literature: Colarusso, Stefania; Conte, Immacolata; Di Filippo, Marcello; Ercolani, Caterina; MacKay, Angela C.; Palumbi, Maria Cecilia; Rico Ferreira, Maria Del Rosario; Stansfield, Ian; Zaramella, Simone; Narjes, Frank; Habermann, Joerg Synlett, 2011 , # 11 p. 1527 - 1532 |
|
~%
(r)-(+)-n-(tert... CAS#:152491-85-5 |
| Literature: Yoo, Dongwon; Seok Oh, Joon; Lee, Dong-Whal; Kim, Young Gyu Journal of Organic Chemistry, 2003 , vol. 68, # 7 p. 2979 - 2982 |
|
~%
(r)-(+)-n-(tert... CAS#:152491-85-5 |
| Literature: Yoo, Dongwon; Seok Oh, Joon; Lee, Dong-Whal; Kim, Young Gyu Journal of Organic Chemistry, 2003 , vol. 68, # 7 p. 2979 - 2982 |
|
~%
(r)-(+)-n-(tert... CAS#:152491-85-5 |
| Literature: Yoo, Dongwon; Seok Oh, Joon; Lee, Dong-Whal; Kim, Young Gyu Journal of Organic Chemistry, 2003 , vol. 68, # 7 p. 2979 - 2982 |
|
~%
(r)-(+)-n-(tert... CAS#:152491-85-5 |
| Literature: Travins, Jeremy M.; Etzkorn, Felicia A. Tetrahedron Letters, 1998 , vol. 39, # 51 p. 9389 - 9392 |
![O-t-butyldimethylsilyl-N-[(1,1-dimethylethoxy)carbonyl]-N-hydroxymethyl-L-serinol structure](https://www.chemsrc.com/caspic/289/518986-06-6.png)
![(4S)-4-[(t-butyldimethylsilyloxy)methyl]-3-[(1,1-dimethylethoxy)carbonyl]-5-oxazolidinone structure](https://www.chemsrc.com/caspic/321/367490-60-6.png)
![O-t-butyldimethylsilyl-N-[(1,1-dimethylethoxy)carbonyl]-N-hydroxymethyl-L-serinal hemiacetal structure](https://www.chemsrc.com/caspic/327/518986-05-5.png)
| Precursor 7 | |
|---|---|
| DownStream 8 | |
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CAS#:171623-07-7| tert-butyl N-[(1R)-2-(tert-butyldimethylsiloxy)-1-(hydroxymethyl)ethyl]carbamate |
| N-Boc-serin-(O-t-butyldimethylsilyl)-ol |
| O-t-butyldimethylsilyl-N-[(1,1-dimethylethoxy)carbonyl]-L-serinol |
| MFCD03093881 |
| (R)-(+)-N-(tert-Butoxycarbonyl)-O-(tert-butyldimethylsilyl)serinol |
| (R)-[1-(tert-butyl-dimethyl-silanyloxymethyl)-2-hydroxy-ethyl]-carbamic acid tert-butyl ester |
| 1,1-dimethylethyl [(1R)-2-{[(1,1-dimethylethyl)(dimethyl)silyl]oxy}-1-(hydroxymethyl)ethyl]carbamate |
| tert-butyl (R)-1-(tert-butyldimethylsilyloxy)-3-hydroxypropan-2-yl carbamate |
| (R)-tert-butyl 1-(tert-butyldimethylsilyloxy)-3-hydroxypropan-2-ylcarbamate |