4-Chloro-2-methylphenol

Suppliers

Names

[ Name ]:
4-Chloro-2-methylphenol

[Synonym ]:
Phenol, 4-chloro-2-methyl-
4-chlorocresol
p-Chloro-o-cresol
4-Chlor-2-methylbenzolol
o-Cresol,4-chloro
2-METHYL-4-CHLOROPHENOL
4-Chloro-2-cresol
Phenol,4-chloro-2-methyl
4-Chloro-2-methylphenol
4-chloro-2-methyl phenol
EINECS 216-381-3
4-chloro-o-cresol
para-chloro-o-cresol
MFCD00002321

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
225.3±20.0 °C at 760 mmHg

[ Melting Point ]:
43-46 °C(lit.)

[ Molecular Formula ]:
C₇H₇ClO

[ Molecular Weight ]:
142.583

[ Flash Point ]:
90.1±21.8 °C

[ Exact Mass ]:
142.018539

[ PSA ]:
20.23000

[ LogP ]:
2.89

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.566

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GO7120000

CHEMICAL NAME :: o-Cresol, 4-chloro-

CAS REGISTRY NUMBER :: 1570-64-5

BEILSTEIN REFERENCE NO. :: 1906684

LAST UPDATED :: 199710

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C7-H7-Cl-O

MOLECULAR WEIGHT :: 142.59

WISWESSER LINE NOTATION :: QR DG B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1320 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 56 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 100 ug/plate

REFERENCE :: TECSDY Toxicological and Environmental Chemistry. (Gordon & Breach Science Pub. Inc., 1 Park Ave., New York, NY 10016) V.3(3/4)- 1981- Volume(issue)/page/year: 14,143,1987

Safety Information

[ Symbol ]:

GHS05, GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H331-H400

[ Precautionary Statements ]:
P261-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P403 + P233

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic;C:Corrosive;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R23;R35;R50

[ Safety Phrases ]:
S26-S36/37/39-S45-S61

[ RIDADR ]:
UN 3437 6.1/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
GO7120000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2908199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

4-Chloro-2-methylphenylboronic acid
(4-chloro-2-methylphenyl)(iso-propoxy)dimethylsilane
5-Chloro-2-hydroxybenzyl alcohol
METHYLMAGNESIUM BROMIDE
2,4-Dichlorophenol
o-cresol
4-Hydroxy-3-methylbenzenesulfonic acid
Diiodomethane
4-Chlorophenol
1-(4-nitrobenzyloxy)-2-methylbenzene

DownStream

5-chlorosalicylic acid
4-Chloro-1-methoxy-2-methylbenzene
MCPA
Oxirane,2-[(4-chloro-2-methylphenoxy)methyl]-
Diethyl 1,2-hydrazinedicarboxylate
2-Methyl-4-chloro-6-bromophenol
5-Chloro-2-methoxybenzoic acid
Acetic acid,2-(4-chloro-2-methylphenoxy)-, ethyl ester
1-(2-bromoethoxy)-4-chloro-2-methylbenzene
diisopropyl bicarbamate

Customs

[ HS Code ]: 2908199090

[ Summary ]:
HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

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