alachlor

Suppliers

Names

[ Name ]:
alachlor

[Synonym ]:
Alanex
Satochlor
2-Chloro-2',6'-diethyl-N-(methoxymethyl)acetanilide
Methachlor
Chimiclor
G1VN1O1&R B2 F2
Acetamide, 2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)-
Lasso
Alachlore
alachlor
Lasagrin
Nitala
Metachlor
Perfect
Micro-Tech
2-Chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide
EINECS 240-110-8
MFCD00041817
2-chloro-2’,6’-diethyl-N-methoxymethylacetanilide
Alapaz
Alochlor

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
404.0±45.0 °C at 760 mmHg

[ Melting Point ]:
39-42°C

[ Molecular Formula ]:
C₁₄H₂₀ClNO₂

[ Molecular Weight ]:
269.767

[ Flash Point ]:
198.1±28.7 °C

[ Exact Mass ]:
269.118256

[ PSA ]:
29.54000

[ LogP ]:
2.92

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.540

[ Water Solubility ]:
0.024 g/100 mL

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AE1225000

CHEMICAL NAME :: Acetanilide, 2-chloro-2',6'-diethyl-N-(methoxymethyl)-

CAS REGISTRY NUMBER :: 15972-60-8

LAST UPDATED :: 199706

DATA ITEMS CITED :: 24

MOLECULAR FORMULA :: C14-H20-Cl-N-O2

MOLECULAR WEIGHT :: 269.80

WISWESSER LINE NOTATION :: G1VN1O1&R B2 F2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 930 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >23400 mg/m3/6H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1200 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 462 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5100 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 3500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 3 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 1200 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 15120 mg/kg/17W-C

TOXIC EFFECTS :: Liver - changes in liver weight Endocrine - changes in thyroid weight Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol)

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2100 mg/kg/21D-I

TOXIC EFFECTS :: Liver - liver function tests impaired Liver - changes in liver weight

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 142 gm/kg/78W-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Lungs, Thorax, or Respiration - tumors

TYPE OF TEST :: Specific locus test

TYPE OF TEST :: Cytogenetic analysis

TYPE OF TEST :: Mutation test systems - not otherwise specified

TYPE OF TEST :: Cytogenetic analysis

MUTATION DATA

TYPE OF TEST :: Cytogenetic analysis

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 10 mg/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 188,241,1987 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

Safety Information

[ Symbol ]:

GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H370-H412

[ Precautionary Statements ]:
P260-P280-P301 + P310 + P330-P302 + P352 + P312-P304 + P340 + P312-P308 + P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R40;R43;R50/53

[ Safety Phrases ]:
S36/37-S46-S60-S61-S62-S45

[ RIDADR ]:
UN 3077

[ RTECS ]:
AE1225000

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
6.1

[ HS Code ]:
2924299034

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

n-chloroacetyl-2,6-diethylaniline
Chloromethyl methyl ether
Formaldehyde
2,6-Diethylaniline
Chloroacetic acid
Trimethyl orthoformate

DownStream

n-chloroacetyl-2,6-diethylaniline
2,6-DIETHYL-ACETANILIDE
N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide
Butachlore
2HYDROXY26DIETHYLNMETHOXYMETHYLACETANILIDE
2HYDROXY26DIETHYLACETANILIDE

Customs

[ HS Code ]: 2924299034

[ Summary ]:
2924299034 n-(3-chloro-4-methylphenyl)-2-methylpentanamide。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

Articles

Environmental friendly method for urban wastewater monitoring of micropollutants defined in the Directive 2013/39/EU and Decision 2015/495/EU.

J. Chromatogr. A. 1418 , 140-9, (2015)

The fate and removal of organic micropollutants in the environment is a demanding issue evidenced by the recent European policy. This work presents an analytical method for the trace quantification of...

Influence of pesticide use in fruit orchards during blooming on honeybee mortality in 4 experimental apiaries.

Sci. Total Environ. 541 , 33-41, (2015)

Samples of dead honey bees (Apis mellifera L.) were collected periodically from 4 different locations during citrus and stone fruit trees blooming season to evaluate the potential impact of agrochemic...

Biodegradation of the acetanilide herbicides alachlor, metolachlor, and propachlor.

Crit. Rev. Microbiol 24(1) , 1-22, (1998)

Alachlor, metolachlor, and propachlor are detoxified in biological systems by the formation of glutathione-acetanilide conjugates. This conjugation is mediated by glutathione-S-transferase, which is p...

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