H-Asp(OMe)-OH·HCl

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Names

[ CAS No. ]:
16856-13-6

[ Name ]:
H-Asp(OMe)-OH·HCl

[Synonym ]:
(2S)-2-Amino-4-methoxy-4-oxobutanoic acid hydrochloride (1:1)
L-Aspartatic Acid 4-Methyl Ester Hydrochloride
4-Methyl L-Aspartate Hydrochloride
EINECS 240-880-5
L-Asparitc acid 4-methyl ester HCl
L-Aspartic acid, 4-methyl ester, hydrochloride (1:1)
MFCD00038972
H-Asp(OMe)-OH.HCl
H-Asp(OMe)-OH·HCl
(S)-2-Amino-4-methoxy-4-oxobutanoic acid hydrochloride
beta-Methyl L-aspartate hydrochloride
β-Methyl L-aspartate hydrochloride

Chemical & Physical Properties

[ Density]:
1.299g/cm3

[ Boiling Point ]:
301.7ºC at 760mmHg

[ Melting Point ]:
191-193°C

[ Molecular Formula ]:
C5H10ClNO4

[ Molecular Weight ]:
183.590

[ Flash Point ]:
136.3ºC

[ Exact Mass ]:
183.029831

[ PSA ]:
89.62000

[ LogP ]:
0.46370

[ Vapour Pressure ]:
0.000242mmHg at 25°C

[ Storage condition ]:
−20°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2922509090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • L-Aspartic acid
  • H-Asp(OMe)-OMe.HCl
  • Methyl acetate

DownStream

  • Z-ASP(OME)-OH
  • L-​Homoserine
  • L-asparagine
  • Boc-L-aspartic acid 4-methyl ester
  • Fmoc-Asp(OMe)-OH
  • beta-Alanine
  • H-Asp(OMe)-OH
  • L-Aspartic acid,N-[N-[(phenylmethoxy)carbonyl]glycyl]-, 4-methyl ester (9CI)
  • N-Benzoyl-L-aspartic acid 4-methyl ester

Customs

[ HS Code ]: 2922509090

[ Summary ]:
2922509090. other amino-alcohol-phenols, amino-acid-phenols and other amino-compounds with oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Syntheses of S-enantiomers of hanishin, longamide B, and longamide B methyl ester from L-aspartic acid beta-methyl ester: establishment of absolute stereochemistry.

J. Org. Chem. 70 , 9081-9084, (2005)

[reaction: see text] Total syntheses of enantiopure hanishin, longamide B, and longamide B methyl ester are described. Absolute configurations of these natural products have been established.

Enzymatic synthesis of a CCK-4 tripeptide fragment.

Di Yi Jun Yi Da Xue Xue Bao 23 , 289-292, (2003)

To synthesize a tripeptide derivative Phac-Met-Asp(OMe)-Phe -NH2, which is a fragment of the gastrin C-terminal tetrapeptide CCK-4, by enzymatic reaction.Three free enzymes, alpha-chymotrypsin, papain...

Practical synthesis of (R)-4-mercaptopyrrolidine-2-thione from L-aspartic acid. Preparation of a novel orally active 1-beta-methylcarbapenem, TA-949.

J. Org. Chem. 65 , 517-522, (2000)

A facile and economical synthesis of a novel orally active 1-beta-methylcarbapenem, TA-949 (1), is described. The key process involves an efficient synthesis of the C-2 side chain (R)-4-mercaptopyrrol...


More Articles

Related Compounds

  • H-Asp(OMe)-OH·HCl
  • H-Asp(OMe)-OH
  • H-Asp(OMe)-OMe.HCl
  • H-Asp-OMe
  • H-D-Asp(Ome)-OH·HCl
  • Boc-L-aspartic acid 4-methyl ester
  • 1-Cyclopropyl-2-(3-fluorophenyl)ethan-1-amine
  • 2-(2-Chlorophenyl)-1-cyclopropylethan-1-amine
  • 2-Methyl-1-(pyrimidin-2-YL)propan-1-amine
  • 1-[2-(cyclopentyloxy)ethyl]-1H-pyrazol-4-amine
  • 1-[2-(Benzyloxy)ethyl]-1H-pyrazol-4-amine
  • (1-Cyclopentylethyl)(ethyl)amine
  • 3-(Trifluoromethyl)-2-thiophenemethanol
  • 1-(2-tert-butoxyethyl)-1H-pyrazol-4-amine
  • (-)-N-(4-Chlorophenyl)-2-(hydroxymethyl)-1-pyrrolidinecarboxamide
  • 3-Fluoro-N,I+/--dipropylbenzenemethanamine
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