Dimethylaminopropionitrile

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Names

[ CAS No. ]:
1738-25-6

[ Name ]:
Dimethylaminopropionitrile

[Synonym ]:
2-DIMETHYLAMINOETHYL CYANIDE
Cyanogum41catalyst
MFCD00001957
3-(Dimethylamino)propanenitrile
3-(DIMETHYLAMINO)PROPIONITRILE
EINECS 217-090-4
Dimethylaminopropion
3-(N,N-dimethylamino)-propionitrile
3-dimethylaminopropannitril
3-(dimethylamino)-propionitril
2-Dimthylaminoethyl cyanide
DMAPN
3-Dimethylaminopropanonitrile
β-Dimethylaminopropionitrile

Chemical & Physical Properties

[ Density]:
0.87 g/mL at 25 °C(lit.)

[ Boiling Point ]:
171 °C750 mm Hg(lit.)

[ Melting Point ]:
−43 °C(lit.)

[ Molecular Formula ]:
C5H10N2

[ Molecular Weight ]:
98.14630

[ Flash Point ]:
145 °F

[ Exact Mass ]:
98.08440

[ PSA ]:
27.03000

[ LogP ]:
0.46168

[ Vapour Pressure ]:
1.24mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.426(lit.)

[ Water Solubility ]:
0.5 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UG1575000
CHEMICAL NAME :
Propionitrile, 3-(dimethylamino)-
CAS REGISTRY NUMBER :
1738-25-6
BEILSTEIN REFERENCE NO. :
0773779
LAST UPDATED :
199710
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C5-H10-N2
MOLECULAR WEIGHT :
98.17
WISWESSER LINE NOTATION :
NC2N1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,923,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,923,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2600 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,923,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00201
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1410 uL/kg
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 10 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO DIMETHYLAMINOPROPIONITRILE-air:min expos to NIAX REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M3293 No. of Facilities: 145 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 1990 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312-H319

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R21;R36/38

[ Safety Phrases ]:
S26-S36/37-S24/25

[ RIDADR ]:
2927

[ WGK Germany ]:
1

[ RTECS ]:
UG1575000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
29269095

Synthetic Route

Precursor & DownStream

Precursor

  • Dimethylamine
  • Acrylonitrile
  • hydracrylonitrile
  • 2-(dimethylaminomethyl)isoindole-1,3-dione
  • Cyanoacetic acid
  • 1-dimethylamino-1-aza-1,3-pentadiene
  • 3-Methoxypropionitrile

DownStream

  • 3-(dimethylamino)-1-phenylpropan-1-one
  • 5-[2-(dimethylamino)ethyl]-1,3,4-thiadiazol-2-amine
  • 1-(Methylamino)anthraquinone
  • 1-(dimethylamino)anthracene-9,10-dione
  • 3-Amino-4,5-dihydro-1-phenylpyrazole
  • 1-Piperidinepropionitrile
  • 4-chloro-N,N-dimethyl-2-nitroaniline
  • hydrochloride of 3-dimethylaminopropionitrile
  • Acrylonitrile
  • 4-N,N-dimethylaminonaphthalene-1,8-dicarboxylic acid anhydride

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

The urotoxic effects of N,N'-dimethylaminopropionitrile. 2. In vivo and in vitro metabolism.

Toxicol. Appl. Pharmacol. 110(1) , 61-9, (1991)

The urotoxicity and metabolism of N,N'-dimethylaminopropionitrile (DMAPN) were investigated in male Sprague-Dawley rats. Animals treated with 525 mg DMAPN/kg or equimolar doses of commercially availab...

Purification of RNA molecules by gel techniques.

Meth. Enzymol. 180 , 14-25, (1989)

[Morbidity study of employees exposed to dimethylaminopropionitrile].

Zentralbl. Arbeitsmed. Arbeitsschutz. Prophyl. Ergonomie 32(5) , 181-4, (1982)


More Articles


Related Compounds

  • 3-Dimethylaminopropionitrile
  • 2-dimethylaminopropionitrile
  • hydrochloride of 3-dimethylaminopropionitrile
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • Methyl 2-hydroxy-3-(trifluoromethylsulfonyloxy)benzoate