phenyl trifluoromethanesulfonate

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Names

[ CAS No. ]:
17763-67-6

[ Name ]:
phenyl trifluoromethanesulfonate

[Synonym ]:
trifluoromethanesulfonyloxybenzene
phenyl triflate
MFCD00192399
Trifluoromethanesulfonic Acid Phenyl Ester
Phenyl TrifluoroMethanesulfonate
phenol triflate

Chemical & Physical Properties

[ Density]:
1.396 g/mL at 25ºC(lit.)

[ Boiling Point ]:
99-100ºC60 mm Hg(lit.)

[ Molecular Formula ]:
C7H5F3O3S

[ Molecular Weight ]:
226.17300

[ Flash Point ]:
160 °F

[ Exact Mass ]:
225.99100

[ PSA ]:
51.75000

[ LogP ]:
2.99580

[ Vapour Pressure ]:
0.0862mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.435(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H311-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
36/37/38-34-24/25

[ Safety Phrases ]:
26-36-45-36/37/39

[ RIDADR ]:
UN 2927 6.1/PG 2

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • triflic anhydride
  • Phenol
  • N,N-Bis(trifluoromethylsulfonyl)aniline
  • 4-Iodophenyl trifluoromethanesulfonate
  • 2-iodophenyl triflate
  • 2-Chlorophenyl Trifluoromethanesulfonate
  • tert-Butyl allylcarbamate
  • trifluoromethanesulfonyl fluoride
  • Trimethyl Phenoxysilane
  • Trifluoromethanesulfonic acid

DownStream

  • 1-Phenylpyrrolidine
  • 1-Phenylpiperidine
  • Phenyl(3-pyridinyl)methanone
  • N,N-DIISOPROPYLANILINE
  • 1-Methyl-4-phenylpiperazine
  • 2-Phenylacetophenone
  • Benzamide
  • 4-Fluoro-alpha-methylstyrene
  • 1-phenylcyclohex-1-ene

Articles

Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel.

J. Am. Chem. Soc. 130(1) , 195-200, (2008)

The asymmetric alpha-arylation of ketones with aryl triflates is described, and the use of this electrophile with nickel and palladium catalysts containing a segphos derivative increases substantially...

One-pot synthesis of carbazoles by palladium-catalyzed N-arylation and oxidative coupling. Watanabe T, et al.

Chem. Commun. (Camb.) 43 , 4516-4518, (2007)

Regioselective arylation of benzanilides with aryl triflates or bromides under palladium catalysis. Kametani Y, et al.

Tetrahedron Lett. 41(15) , 2655-2658, (2000)


More Articles

Related Compounds

  • 4-Iodophenyl trifluoromethanesulfonate
  • 2-formylphenyl trifluoromethanesulfonate
  • 2-benzylphenyl trifluoromethanesulfonate
  • .o-allylphenyl trifluoromethanesulfonate
  • 4-fluorophenyl trifluoromethanesulfonate
  • 4-Carboxyphenyl trifluoromethanesulfonate
  • 1-(4-chlorobenzyl)-3-((1-(3-fluorophenyl)-1H-tetrazol-5-yl)methyl)urea
  • 1-((1-(3-fluorophenyl)-1H-tetrazol-5-yl)methyl)-3-(4-methoxyphenethyl)urea
  • 1-((1-(3-fluorophenyl)-1H-tetrazol-5-yl)methyl)-3-(naphthalen-1-ylmethyl)urea
  • 3-[3-(Trifluoromethyl)phenyl]pyridin-2-amine
  • cyclopropyl(1H-pyrrol-3-yl)methanone
  • 1-Benzyl-4-(4-chloro-2-fluorobenzyl)-4-piperidinol
  • 1-(3-chlorophenyl)-3-((1-(4-chlorophenyl)-1H-tetrazol-5-yl)methyl)urea
  • 1-((1-(4-chlorophenyl)-1H-tetrazol-5-yl)methyl)-3-(4-fluorophenyl)urea
  • 1-((1-(4-chlorophenyl)-1H-tetrazol-5-yl)methyl)-3-phenethylurea
  • 5-ethyl-2-phenyl-7-(1,2,3,4-tetrahydroquinoline-1-carbonyl)-2H-pyrazolo[4,3-c]pyridin-3(5H)-one
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