phenyl trifluoromethanesulfonate

phenyl trifluoromethanesulfonate Structure
phenyl trifluoromethanesulfonate structure
Common Name phenyl trifluoromethanesulfonate
CAS Number 17763-67-6 Molecular Weight 226.17300
Density 1.396 g/mL at 25ºC(lit.) Boiling Point 99-100ºC60 mm Hg(lit.)
Molecular Formula C7H5F3O3S Melting Point N/A
MSDS Chinese USA Flash Point 160 °F
Symbol GHS05 GHS06
GHS05, GHS06
Signal Word Danger

Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel.

J. Am. Chem. Soc. 130(1) , 195-200, (2008)

The asymmetric alpha-arylation of ketones with aryl triflates is described, and the use of this electrophile with nickel and palladium catalysts containing a segphos derivative increases substantially the scope of highly enantioselective arylations of ketone ...

One-pot synthesis of carbazoles by palladium-catalyzed N-arylation and oxidative coupling. Watanabe T, et al.

Chem. Commun. (Camb.) 43 , 4516-4518, (2007)

Regioselective arylation of benzanilides with aryl triflates or bromides under palladium catalysis. Kametani Y, et al.

Tetrahedron Lett. 41(15) , 2655-2658, (2000)

Palladium-catalyzed asymmetric arylation of 2, 3-dihydrofuran with phenyl triflate. A novel asymmetric catalysis involving a kinetic resolution process. Ozawa F, et al.

Organometallics 12(10) , 4188-4196, (1993)

Palladium cross-coupling reactions of aryl fluorosulfonates: an alternative to triflate chemistry. Roth GP and Fuller CE.

J. Org. Chem. 56(11) , 3493-3496, (1991)