tert-Butoxy(chloro)diphenylsilane

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Names

[ CAS No. ]:
17922-24-6

[ Name ]:
tert-Butoxy(chloro)diphenylsilane

[Synonym ]:
Chloro[(2-methyl-2-propanyl)oxy]diphenylsilane
diphenyl-t-butoxysilyl chloride
tert-Butoxydiphenylsilyl Chloride
MFCD00077672
tert-Butoxy(chloro)diphenylsilane
tert-butyloxydiphenylsilyl chloride
t-butoxydiphenylsilyl chloride
tert-Butoxychlorodiphenylsilane
tert-Butoxy-diphenylchlorosilane
Benzene, 1,1'-[chloro(1,1-dimethylethoxy)silylene]bis-
tert-Butoxydiphenylchlorosilane

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
331.0±15.0 °C at 760 mmHg

[ Molecular Formula ]:
C16H19ClOSi

[ Molecular Weight ]:
290.860

[ Flash Point ]:
128.2±12.5 °C

[ Exact Mass ]:
290.089355

[ PSA ]:
9.23000

[ LogP ]:
7.36

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.546

[ Storage condition ]:
−20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2986 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Dichlorodiphenylsilane
  • tert-Butanol

DownStream

  • (3R,4S)-tert-Butyl 2-oxo-4-phenyl-3-(triethylsilyloxy)azetidine-1-carboxylate

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Gillard, J.W., et al.

J. Org. Chem. 53 , 2602, (1988)

M. Grotli, B.S. Sproat

J. Chem. Soc. Chem. Commun. , 495, (1995)


More Articles

Related Compounds

  • chloro-dimethyl-[(2-methylpropan-2-yl)oxy]silane
  • tert-butoxy(methyl)diphenylsilane
  • tert-butoxy(dodecyloxy)diphenylsilane
  • tert-Butyl(chloro)diphenylsilane
  • tert-butyl-[4-[(2S)-oxolan-2-yl]butoxy]-diphenylsilane
  • tert-butyl-{(S)-3-[(1R,2R)-2-((S)-2,2-dimethyl[1,3]dioxolan-4-yl)cyclopropyl]butoxy}diphenylsilane
  • 1-{2-[1-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclobutyl]acetyl}-6-methylpiperidine-3-carboxylic acid
  • 1-[5-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanoyl]-6-methylpiperidine-3-carboxylic acid
  • 1-[1-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclopropanecarbonyl]-6-methylpiperidine-3-carboxylic acid
  • 1-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanoyl]-6-methylpiperidine-3-carboxylic acid
  • 1-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylpropanoyl]-5-hydroxypiperidine-3-carboxylic acid
  • 1-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanoyl]-5-hydroxypiperidine-3-carboxylic acid
  • 1-{2-[1-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclobutyl]acetyl}-5-hydroxypiperidine-3-carboxylic acid
  • 2-[2-(cyclopropylmethyl)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-N-(2-hydroxyethyl)propanamido]acetic acid
  • 2-({2-[2-(cyclopropylmethyl)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanamido]ethyl}sulfanyl)acetic acid
  • 3-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-(1H-pyrrol-2-yl)propanamido]-2-methylpropanoic acid
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