pentachloroanisole

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Names

[ CAS No. ]:
1825-21-4

[ Name ]:
pentachloroanisole

[Synonym ]:
Methyl pentachlorophenyl ether
2,3,4,5,6-pentachloroanisole
pentachlorophenol anisole
Ether,methyl pentachlorophenyl
Pentachloromethoxybenzene
Methyl pentachlorophenate
Benzene,pentachloromethoxy
Anisole,2,3,4,5,6-pentachloro
Pentachlorophenyl methyl ether
Pentachloranisole
Methyl pentachlorophenyl ester
pentachloroanisol
Pentachloroanisole

Chemical & Physical Properties

[ Density]:
1.618g/cm3

[ Boiling Point ]:
321.5ºC at 760mmHg

[ Melting Point ]:
108-110℃

[ Molecular Formula ]:
C7H3Cl5O

[ Molecular Weight ]:
280.36300

[ Flash Point ]:
127.1ºC

[ Exact Mass ]:
277.86300

[ PSA ]:
9.23000

[ LogP ]:
4.96220

[ Vapour Pressure ]:
0.000557mmHg at 25°C

[ Index of Refraction ]:
1.577

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BZ8820000
CHEMICAL NAME :
Anisole, 2,3,4,5,6-pentachloro-
CAS REGISTRY NUMBER :
1825-21-4
BEILSTEIN REFERENCE NO. :
2052667
LAST UPDATED :
199710
DATA ITEMS CITED :
15
MOLECULAR FORMULA :
C7-H3-Cl5-O
MOLECULAR WEIGHT :
280.35
WISWESSER LINE NOTATION :
GR BG CG DG EG FO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
318 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - tremor Behavioral - muscle weakness
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
281 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - tremor Behavioral - muscle weakness
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2 gm/kg/16D-I
TOXIC EFFECTS :
Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5200 mg/kg/13W-I
TOXIC EFFECTS :
Liver - hepatitis (hepatocellular necrosis), zonal Kidney, Ureter, Bladder - changes in bladder weight Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1600 mg/kg/16D-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2600 mg/kg/13W-I
TOXIC EFFECTS :
Liver - other changes Kidney, Ureter, Bladder - changes in bladder weight
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10300 mg/kg/2Y-I
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Endocrine - tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
20800 mg/kg/2Y-I
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Liver - angiosarcoma Endocrine - tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
7420 mg/kg
SEX/DURATION :
female 23 week(s) pre-mating female 1-22 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
724 mg/kg
SEX/DURATION :
female 23 week(s) pre-mating female 1-22 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Rodent - mouse Lymphocyte
DOSE/DURATION :
75 mg/L
REFERENCE :
ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 9,143,1987

Safety Information

[ Symbol ]:

GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H400

[ Precautionary Statements ]:
P273

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R22

[ RIDADR ]:
UN 2811

[ WGK Germany ]:
3.0

[ RTECS ]:
BZ8820000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2909309090

Precursor & DownStream

Precursor

  • Peratox
  • methyl iodide
  • Hexachlorobenzene
  • Dimethyl sulfate
  • 4-Iodoanisole
  • Anisole
  • diazomethane
  • Pentachloronitrobenzene
  • Sodium Methylate

DownStream

  • 1-Chloro-4-methoxybenzene
  • 3-Chloroanisole
  • 2-Chloroanisole
  • Anisole

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Responses of the L5178Y tk+/tk- mouse lymphoma cell forward mutation assay to coded chemicals. I: Results for nine compounds.

Environ. Mutagen. 9(2) , 143-60, (1987)

Nine substances were tested for their mutagenic potential in the L5178Y tk+/tk- mouse lymphoma cell forward mutation assay, by means of procedures based upon those described by Clive and Spector (Muta...

Involvement of cytochrome P450 in pentachlorophenol transformation in a white rot fungus Phanerochaete chrysosporium.

PLoS ONE 7(9) , e45887, (2012)

The occurrence of cytochrome P450 and P450-mediated pentachlorophenol oxidation in a white rot fungus Phanerochaete chrysosporium was demonstrated in this study. The carbon monoxide difference spectra...

Determination of halophenolic wood preservant traces in milk using headspace solid-phase microextraction and gas chromatography-mass spectrometry.

J. Chromatogr. A. 1215(1-2) , 1-7, (2008)

Extraction of 2,4,6-tribromophenol (TBP), pentachlorophenol (PCP) and pentachloroanisole (PCA) from whole fat cow milk using headspace solid-phase microextraction (HS-SPME) with polyacrylate (PA) and ...


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Related Compounds

  • Pentachloroanisole-d3
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  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
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  • tert-Butyl-DL-alanine
  • 4-Carboxymethyl-5-oxo-2-phenyl-piperazine-1-carboxylic acid tert-butyl ester
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide