Methyl indolyl-3-glyoxylate

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Names

[ CAS No. ]:
18372-22-0

[ Name ]:
Methyl indolyl-3-glyoxylate

[Synonym ]:
methyl indolyl-3-glyoxylate
(1H-indol-3-yl)oxoacetic acid methyl ester
Methyl 3-indoleglyoxylate
MFCD00047173
2-(3-Indolyl)-2-oxoessigsaeure-methylester
3-indoleglyoxylic acid methyl ester
Indole-3-glyoxylic acid methyl ester
Methyl 2-(indol-3-yl)-2-oxoacetate
Methyl Indol-3-Glyoxylate
Methyl 1H-indol-3-yl(oxo)acetate
methyl indole-3-glyoxylate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
383.2±15.0 °C at 760 mmHg

[ Melting Point ]:
227-230 °C(lit.)

[ Molecular Formula ]:
C11H9NO3

[ Molecular Weight ]:
203.194

[ Flash Point ]:
185.6±20.4 °C

[ Exact Mass ]:
203.058243

[ PSA ]:
59.16000

[ LogP ]:
1.19

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.636

[ Stability ]:
Temperature Sensitive

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • 1H-Indol-3-yl(oxo)acetic acid
  • indole-3-glyoxylyl chloride
  • Sodium Methylate
  • Indole
  • (Trimethylsilyl)diazomethane
  • Oxalyl chloride
  • methyl oxalyl chloride

DownStream

  • 2-(1-METHYL-1H-INDOL-3-YL)-2-OXOACETIC ACID METHYL ESTER
  • 1H-Indole-3-acetamide,N,N-dimethyl-α-oxo-
  • isodidemnimide A
  • Tryptophol
  • D,L-3-Indolylglycine
  • tert-butyl-[2-(1H-indol-3-yl)ethoxy]-dimethylsilane
  • Methyl (2E)-(hydroxyimino)(1H-indol-3-yl)acetate
  • Bisindolylmaleimide IV
  • n-methylbis(indol-3-yl)maleimide
  • Bisindolylmaleimide I (GF109203X)

Articles

Lasting chemiluminescence of 3-indoleglyoxylyl chloride and its enhancement.

Anal. Sci. 19(1) , 123-7, (2003)

The chemiluminescence (CL) intensities of various indole derivatives substituted with a glyoxylyl group at the 3-position and a hydroxyl group at the 5-position of the indole ring were compared upon t...


More Articles

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