5-Bromo-2-furaldehyde

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Names

[ CAS No. ]:
1899-24-7

[ Name ]:
5-Bromo-2-furaldehyde

[Synonym ]:
5-Bromofurfural
5-bromofuran-2-carbaldehyde
5-Bromofurancarboxaldehyde
5-bromo-2-furancarboxaldehyde
5-bromofuran-2-yl carbaldehyde
2-Furaldehyde, 5-bromo-
2-Furancarboxaldehyde, 5-bromo-
5'-bromo-furan-2'-carboxaldehyde
5-Bromo-2-furaldehyde
5-bromo-furfurol
5-bromo-2-furfural
2-Furancarboxaldehyde,5-bromo
MFCD00159501

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
222.9±20.0 °C at 760 mmHg

[ Melting Point ]:
82-85 °C(lit.)

[ Molecular Formula ]:
C5H3BrO2

[ Molecular Weight ]:
174.980

[ Flash Point ]:
88.6±21.8 °C

[ Exact Mass ]:
173.931641

[ PSA ]:
30.21000

[ LogP ]:
1.77

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.573

[ Storage condition ]:
Refrigerator

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H315-H319-H332-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S36-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2932190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • N-methyl-N-methoxy-5-bromofuran-2-carboxamide
  • 5-Bromo-2-furonitrile
  • 1-(5-bromofur-2-il)-2-bromo-2-nitroethene
  • Furfural
  • (5-formylfuran-2-yl)(triphenyl-λ5-phosphanyl)gold
  • furfurylidene di(acetate)
  • 5-Bromofuroic acid
  • bis-(5-formyl-[2]furyl)-mercury
  • bis-(5-hydroxymethyl-[2]furyl)-mercury

DownStream

  • Methyl 4-(5-formylfuran-2-yl)benzoate
  • 5-(4-chlorophenyl)-2-furaldehyde
  • 5-Methyl-2-furanmethanol
  • 5-[2-(TRIFLUOROMETHOXY)PHENYL]-2-FURALDEHYDE
  • 5-MORPHOLIN-4-YL-FURAN-2-CARBALDEHYDE
  • 5-Thien-2-yl-2-furaldehyde
  • 5-(2-chlorophenyl)furfural
  • 1-(4-AMINO-2-FLUORO-5-METHOXY-PHENYL)-ETHANONE
  • (5-formylfuran-2-yl)-trimethylazanium,bromide
  • 5-(azepan-1-yl)furan-2-carbaldehyde

Customs

[ HS Code ]: 2932190090

[ Summary ]:
2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

5-Substituted-2-furaldehydes: a synthetic protocol utilizing an organozinc route.

J. Org. Chem. 78(5) , 1984-93, (2013)

Facile synthetic routes for the preparation of a wide range of 5-substituted 2-furaldehydes have been revealed. They were accomplished through either Pd-catalyzed cross-coupling reaction of various ar...

From furans to anilines: toward one-pot two-step amination/diels-alder sequences.

J. Org. Chem. 73(6) , 2191-7, (2008)

Selective metal-free amination and Diels-Alder reactions are described in the furan series, leading to polysubstituted anilines or to stable oxabicyclic adducts in high yield. Interestingly, anilines ...

Efficient coupling of heteroaryl bromides with arylboronic acids in the presence of a palladium-tetraphosphine catalyst. Feuerstein M, et al.

Tetrahedron Lett. 42(23) , 5659-62, (2001)


More Articles

Related Compounds

  • 5-Bromo-2-(2-methyl-2-propanyl)pyridine
  • 5-bromo-2-chloro-N,N-diethylpyrimidin-4-amine
  • 5-bromo-2-N,2-N,4-N,4-N-tetramethylpyrimidine-2,4-diamine
  • 5-bromo-2-(dimethylamino)-1H-pyrimidin-6-one
  • 3-Bromo-6-chloro-2,4-dimethyl-5-nitropyridine
  • 5-bromo-2-chloro-4-[(2-methylpropan-2-yl)oxy]pyrimidine
  • 4-Hydroxy-2-(3-methylthiophenyl)pyridine
  • 4-(4-Methylthiophenyl)nicotinic acid
  • 6-Amino-3-(4-methylthiophenyl)picolinic acid
  • 4-Hydroxy-2-(4-methylthiophenyl)pyridine
  • 6-Amino-3-(2-fluoro-3-methoxyphenyl)picolinic acid
  • 6-Amino-3-(3-fluoro-4-methoxyphenyl)picolinic acid
  • 6-Amino-3-(4-fluoro-3-methoxyphenyl)picolinic acid
  • 6-Amino-3-(5-fluoro-2-methoxyphenyl)picolinic acid
  • 6-Amino-3-(2-chloro-4-methylphenyl)picolinic acid
  • 6-Amino-3-(3-chloro-4-methylphenyl)picolinic acid
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