(Perfluorobutyl)ethylene

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Names

[ CAS No. ]:
19430-93-4

[ Name ]:
(Perfluorobutyl)ethylene

[Synonym ]:
3,3,4,4,5,5,6,6,6-Nonafluoro-1-hexene
3,3,4,4,5,5,6,6,6-nonafluorohexene
(Perfluorobutyl)ethylene
1-Hexene,3,3,4,4,5,5,6,6,6-nonafluoro
1H,1H,2H-Perfluoro-1-hexene
2,2,3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene
MFCD00042338
Perfluorobutylethylene
1h,1h,2h-nonafluorohex-1-ene
EINECS 243-053-7

Chemical & Physical Properties

[ Density]:
1.452 g/mL at 25 °C(lit.)

[ Boiling Point ]:
59-60 °C(lit.)

[ Molecular Formula ]:
C6H3F9

[ Molecular Weight ]:
246.07400

[ Flash Point ]:
1 °F

[ Exact Mass ]:
246.00900

[ LogP ]:
3.64060

[ Vapour density ]:
8.5 (vs air)

[ Vapour Pressure ]:
332mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.3(lit.)

[ Water Solubility ]:
acetone, MEK and trichloroethylene: soluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MP7360000
CHEMICAL NAME :
1-Hexene, 3,3,4,4,5,5,6,6-nonafluoro-
CAS REGISTRY NUMBER :
19430-93-4
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C6-H3-F9

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>25 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CRTXB2 CRC Critical Reviews in Toxicology. (CRC Press, Inc., 2000 Corporate Blvd., NW, Boca Raton, FL 33431) V.1- 1971- Volume(issue)/page/year: 21,149,1990
TYPE OF TEST :
LC - Lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>7178 ppm/1H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CRTXB2 CRC Critical Reviews in Toxicology. (CRC Press, Inc., 2000 Corporate Blvd., NW, Boca Raton, FL 33431) V.1- 1971- Volume(issue)/page/year: 21,149,1990

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
F:Flammable;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S16-S29-S33

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
MP7360000

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2903399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1,3-bis(1-iodo-3,3,4,4,5,5,6,6,6-nonafluorohexan-1-yl)tetramethyldisiloxane
  • fluorodimethyl(3,3,4,4,5,5,6,6,6-nonafluorohex-1-en-1-yl)silane
  • 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane
  • POTASSIUM ACRYLATE
  • 1H,1H,2H,2H-Perfluorohexyl iodide
  • Diethyl malonate
  • 1-Bromo-3,3,4,4,5,5,6,6,6-nonafluorohexane

DownStream

  • (1-ETHYL-3-PYRROLIDINYL)-N-METHYLMETHANAMINE
  • (N-BUTYLAMINO)ACETONITRILE
  • 3,3,4,4,5,5,6,6,6-Nonafluoro-1-hexanol
  • 3,3,4,4,5,5,6,6,6-nonafluorohexan-2-ol
  • methyl(3,3,4,4,5,5,6,6,6-nonafluorohexyl)silane
  • NONAFLUOROPENTANAL HYDRATE
  • NONAFLUOROHEXYLTRICHLOROSILANE
  • acetic acid,2-bromo-3,3,4,4,5,5,6,6,6-nonafluorohexan-1-ol
  • 2-bromo-3,3,4,4,5,5,6,6,6-nonafluorohexan-1-ol
  • 3,3,4,4,5,5,6,6,6-nonafluorohex-1-yne

Customs

[ HS Code ]: 2903399090

[ Summary ]:
2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Atmospheric chemistry of CF3CH=CH2 and C4F9CH=CH2: products of the gas-phase reactions with Cl atoms and OH radicals.

J. Phys. Chem. A 111(5) , 909-15, (2007)

FTIR-smog chamber techniques were used to study the products of the Cl atom and OH radical initiated oxidation of CF3CH=CH2 in 700 Torr of N2/O2, diluent at 296 K. The Cl atom initiated oxidation of C...

Toxicology of fluorine-containing monomers.

Crit. Rev. Toxicol. 21(2) , 149-70, (1990)

Fluorine-containing monomers form the basis for production of a large number of commercially important polymers. Most of the polymerization occurs as gas-phase reactions, hence the hazards associated ...

4-week inhalation toxicity study with a mixture of dichloroethylene and perfluorobutylethylene in rats.

Inhal. Toxicol. 14(8) , 773-87, (2002)

Inhalation studies were conducted to determine the potential subchronic toxicity of a mixture of trans-1,2-dichloroethylene (70%), cis-1,2-dichloroethylene (5%), and perfluorobutylethylene (25%). Grou...


More Articles

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