(Perfluorobutyl)ethylene

Modify Date: 2024-01-02 11:38:05

(Perfluorobutyl)ethylene Structure
(Perfluorobutyl)ethylene structure
 Common Name (Perfluorobutyl)ethylene
CAS Number 19430-93-4 Molecular Weight 246.07400
Density 1.452 g/mL at 25 °C(lit.) Boiling Point 59-60 °C(lit.)
Molecular Formula C6H3F9 Melting Point N/A
MSDS Chinese USA Flash Point 1 °F
Symbol GHS02
GHS02		 Signal Word Danger

 Names

Name 3,3,4,4,5,5,6,6,6-nonafluorohex-1-ene
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.452 g/mL at 25 °C(lit.)
Boiling Point 59-60 °C(lit.)
Molecular Formula C6H3F9
Molecular Weight 246.07400
Flash Point 1 °F
Exact Mass 246.00900
LogP 3.64060
Vapour density 8.5 (vs air)
Vapour Pressure 332mmHg at 25°C
Index of Refraction n20/D 1.3(lit.)
Water Solubility acetone, MEK and trichloroethylene: soluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MP7360000
CHEMICAL NAME :
1-Hexene, 3,3,4,4,5,5,6,6-nonafluoro-
CAS REGISTRY NUMBER :
19430-93-4
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C6-H3-F9

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>25 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CRTXB2 CRC Critical Reviews in Toxicology. (CRC Press, Inc., 2000 Corporate Blvd., NW, Boca Raton, FL 33431) V.1- 1971- Volume(issue)/page/year: 21,149,1990
TYPE OF TEST :
LC - Lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>7178 ppm/1H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CRTXB2 CRC Critical Reviews in Toxicology. (CRC Press, Inc., 2000 Corporate Blvd., NW, Boca Raton, FL 33431) V.1- 1971- Volume(issue)/page/year: 21,149,1990

 Safety Information

Symbol GHS02
GHS02
Signal Word Danger
Hazard Statements H225
Precautionary Statements P210
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)
Hazard Codes F:Flammable;
Risk Phrases R11
Safety Phrases S16-S29-S33
RIDADR UN 1993 3/PG 2
WGK Germany 3
RTECS MP7360000
Packaging Group II
Hazard Class 3
HS Code 2903399090

 Synthetic Route

1,3-bis(1-iodo-3,3,4,4,5,5,6,6,6-nonafluorohexan-1-yl)tetramethyldisiloxane structure

1,3-bis(1-iodo-...

CAS#:1374104-94-5

~91%

(Perfluorobutyl)ethylene Structure

(Perfluorobutyl...

CAS#:19430-93-4

Literature: Csapo, Agnes; Rabai, Jozsef Journal of Fluorine Chemistry, 2012 , vol. 144, p. 79 - 85,7
1,1,3,3-tetramethyl-1,3-bis(3,3,4,4,5,5,6,6,6-nonafluorohex-1-en-1-yl)disiloxane structure

1,1,3,3-tetrame...

CAS#:1374104-96-7

~75%

(Perfluorobutyl)ethylene Structure

(Perfluorobutyl...

CAS#:19430-93-4

Literature: Csapo, Agnes; Rabai, Jozsef Journal of Fluorine Chemistry, 2012 , vol. 144, p. 79 - 85,7
fluorodimethyl(3,3,4,4,5,5,6,6,6-nonafluorohex-1-en-1-yl)silane structure

fluorodimethyl(...

CAS#:1374104-99-0

~75%

(Perfluorobutyl)ethylene Structure

(Perfluorobutyl...

CAS#:19430-93-4

Literature: Csapo, Agnes; Rabai, Jozsef Journal of Fluorine Chemistry, 2012 , vol. 144, p. 79 - 85,7
1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane structure

1,1,1,2,2,3,3,4...

CAS#:2043-57-4

POTASSIUM ACRYLATE structure

POTASSIUM ACRYLATE

CAS#:10192-85-5

~%

1H,1H,2H,2H-Nonafluorohexyl Acrylate structure

1H,1H,2H,2H-Non...

CAS#:52591-27-2

(Perfluorobutyl)ethylene Structure

(Perfluorobutyl...

CAS#:19430-93-4

Literature: EP1486482 A1, ; Page 5; 6 ;
1H,1H,2H,2H-Perfluorohexyl iodide structure

1H,1H,2H,2H-Per...

CAS#:2043-55-2

POTASSIUM ACRYLATE structure

POTASSIUM ACRYLATE

CAS#:10192-85-5

~%

1H,1H,2H,2H-Nonafluorohexyl Acrylate structure

1H,1H,2H,2H-Non...

CAS#:52591-27-2

(Perfluorobutyl)ethylene Structure

(Perfluorobutyl...

CAS#:19430-93-4

Detail
Literature: EP1486482 A1, ; Page 5; 6 ;
1H,1H,2H,2H-Perfluorohexyl iodide structure

1H,1H,2H,2H-Per...

CAS#:2043-55-2

Diethyl malonate structure

Diethyl malonate

CAS#:105-53-3

~0%

(Perfluorobutyl)ethylene Structure

(Perfluorobutyl...

CAS#:19430-93-4

diethyl 2-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)malonate structure

diethyl 2-(3,3,...

CAS#:36389-98-7

Literature: Trabelsi; Szoenyi; Geribaldi Journal of Fluorine Chemistry, 2001 , vol. 107, # 1 p. 177 - 181
1-Bromo-3,3,4,4,5,5,6,6,6-nonafluorohexane structure

1-Bromo-3,3,4,4...

CAS#:38436-14-5

~%

(Perfluorobutyl)ethylene Structure

(Perfluorobutyl...

CAS#:19430-93-4

Literature: Journal of Organic Chemistry, , vol. 38, p. 1615 - 1616
1H,1H,2H,2H-Perfluorohexyl iodide structure

1H,1H,2H,2H-Per...

CAS#:2043-55-2

~%

(Perfluorobutyl)ethylene Structure

(Perfluorobutyl...

CAS#:19430-93-4

Literature: Phosphorus and the Related Group V Elements, , vol. 4, p. 173 - 178

 Customs

HS Code 2903399090
Summary 2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

 Articles3

More Articles
Atmospheric chemistry of CF3CH=CH2 and C4F9CH=CH2: products of the gas-phase reactions with Cl atoms and OH radicals.

J. Phys. Chem. A 111(5) , 909-15, (2007)

FTIR-smog chamber techniques were used to study the products of the Cl atom and OH radical initiated oxidation of CF3CH=CH2 in 700 Torr of N2/O2, diluent at 296 K. The Cl atom initiated oxidation of C...

Toxicology of fluorine-containing monomers.

Crit. Rev. Toxicol. 21(2) , 149-70, (1990)

Fluorine-containing monomers form the basis for production of a large number of commercially important polymers. Most of the polymerization occurs as gas-phase reactions, hence the hazards associated ...

4-week inhalation toxicity study with a mixture of dichloroethylene and perfluorobutylethylene in rats.

Inhal. Toxicol. 14(8) , 773-87, (2002)

Inhalation studies were conducted to determine the potential subchronic toxicity of a mixture of trans-1,2-dichloroethylene (70%), cis-1,2-dichloroethylene (5%), and perfluorobutylethylene (25%). Grou...

 Synonyms

3,3,4,4,5,5,6,6,6-Nonafluoro-1-hexene
3,3,4,4,5,5,6,6,6-nonafluorohexene
(Perfluorobutyl)ethylene
1-Hexene,3,3,4,4,5,5,6,6,6-nonafluoro
1H,1H,2H-Perfluoro-1-hexene
2,2,3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene
MFCD00042338
Perfluorobutylethylene
1h,1h,2h-nonafluorohex-1-ene
EINECS 243-053-7
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