DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)

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Names

[ CAS No. ]:
203714-71-0

[ Name ]:
DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)

[Synonym ]:
Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II)
Dichloro(2-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium (II)
Hoveyda-Grubbs Catalyst 1st Generation
Hoveyda-Grubbs first generation catalyst
Phosphine, tricyclohexyl-, compd. with dichloro[[2-(1-methylethoxy)phenyl]methylene]ruthenium (1:1)
Dichloro(2-isopropoxybenzylidene)ruthenium - tricyclohexylphosphine (1:1)
MFCD03453042
dichloro(tricyclohexylphosphine)-(o-isopropoxy-phenylmethylene)ruthenium(II)

Chemical & Physical Properties

[ Boiling Point ]:
383.4ºC at 760 mmHg

[ Melting Point ]:
195-197ºC(lit.)

[ Molecular Formula ]:
C28H45Cl2OPRu

[ Molecular Weight ]:
600.606

[ Flash Point ]:
195.6ºC

[ Exact Mass ]:
600.162903

[ PSA ]:
22.82000

[ LogP ]:
10.01880

[ Vapour Pressure ]:
9.7E-06mmHg at 25°C

[ Storage condition ]:
2~8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H228

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
F+

[ RIDADR ]:
UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all

Precursor & DownStream

Precursor

  • Benzylidenebis(tricyclohexylphosphine)dichlororuthenium
  • 1-ethenyl-2-propan-2-yloxybenzene

DownStream

Articles

Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts.

Chem. Rev. 110 , 1746, (2010)

Olefin Metathesis and Beyond A list of abbreviations can be found at the end of this article.

Angew. Chem. Int. Ed. Engl. 39 , 3012, (2000)

The advent of well-defined catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups has revolutionized the field. The past decad...

The development of L2X2Ru=CHR olefin metathesis catalysts: an organometallic success story.

Acc. Chem. Res. 34 , 18, (2001)

In recent years, the olefin metathesis reaction has attracted widespread attention as a versatile carbon-carbon bond-forming method. Many new applications have become possible because of major advance...


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