ethyl 1,3-dithiolane-2-carboxylate

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Names

[ CAS No. ]:
20461-99-8

[ Name ]:
ethyl 1,3-dithiolane-2-carboxylate

[Synonym ]:
2-Carboethoxydithiolane
1,3-Dithiolane-2-carboxylic Acid Ethyl Ester
Ethyl-1,3-dithiolan-2-carboxylat
Ethyl 1,3-dithiolane-2-carboxylate
ethyl dithiolane-2-carboxylate
2-ethoxycarbonyl-1,3-dithiolane
ethyl 2,2-(1,3-dithiolane-2-yl)acetate
MFCD00005411
EINECS 243-837-9

Chemical & Physical Properties

[ Density]:
1.249 g/mL at 25 °C(lit.)

[ Boiling Point ]:
85 °C0.1 mm Hg(lit.)

[ Molecular Formula ]:
C6H10O2S2

[ Molecular Weight ]:
178.27200

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
178.01200

[ PSA ]:
76.90000

[ LogP ]:
1.35560

[ Vapour Pressure ]:
0.013mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.539(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
3334

[ WGK Germany ]:
3

[ HS Code ]:
2934999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1,2-Ethanedithiol
  • Ethyl dichloroacetate
  • Ethanol
  • ethane-1,2-dithiol, monopotassium salt

DownStream

  • 2-(1,3-dithiolan-2-ylidene)ethoxymethoxy-trimethylsilane
  • 2-(1,3-dithiolan-2-ylidene)-1,3-dithiolane
  • 1,3-dithiolane-2-methanol
  • 7-acetyl-6-methoxy-9-oxa-1,4-dithiaspiro[4.5]decan-10-one
  • 1,3-Dithiolane-2-carboxylicacid

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

General strategy for the syntheses of corynanthe, tacaman, and oxindole alkaloids.

J. Org. Chem. 71(17) , 6547-61, (2006)

We report herein the total synthesis of the corynanthe alkaloid dihydrocorynantheol and the formal syntheses of the indole alkaloids tacamonine, rhynchophylline, and hirsutine. The strategies for asse...

Stereodivergent synthesis of enantiopure cis- and trans-3-Ethyl-4-piperidineacetates.

Org. Lett. 4(16) , 2787-90, (2002)

[reaction: see text] Starting from a common chiral bicyclic lactam 11, enantiopure trans- or cis-3-ethyl-4-piperidineacetate derivatives are obtained by conjugate addition of an enolate or a cuprate t...

H. Paulson, W. Koebernick

Chem. Ber. 110 , 2127, (1977)


More Articles

Related Compounds

  • ethyl 2-methyl-1,3-dithiolane-2-carboxylate
  • ethyl 4,5-di-tert-butyl-1,3-dithiolane-2-carboxylate
  • ethyl 2-(2-(hydroxymethyl)-3-oxohexyl)-1,3-dithiolane-2-carboxylate
  • ethyl 2-(2-(hydroxymethyl)-3-oxopentyl)-1,3-dithiolane-2-carboxylate
  • ethyl 2-(2-(hydroxymethyl)-3-oxobutyl)-1,3-dithiolane-2-carboxylate
  • ethyl 2-(4-nitro-1H-indol-3-yl)-1,3-dithiolane-2-carboxylate
  • 2-methyl-N-(2-((2-(methylamino)-2-oxoethyl)thio)-4-phenylthiazol-5-yl)benzamide
  • 3-methyl-N-(2-((2-(methylamino)-2-oxoethyl)thio)-4-phenylthiazol-5-yl)benzamide
  • 2-methoxy-N-(2-((2-(methylamino)-2-oxoethyl)thio)-4-phenylthiazol-5-yl)benzamide
  • 2-ethoxy-N-(2-((2-(methylamino)-2-oxoethyl)thio)-4-phenylthiazol-5-yl)benzamide
  • 3,5-dimethoxy-N-(2-((2-(methylamino)-2-oxoethyl)thio)-4-phenylthiazol-5-yl)benzamide
  • 2-fluoro-N-(2-((2-(methylamino)-2-oxoethyl)thio)-4-phenylthiazol-5-yl)benzamide
  • 2,6-difluoro-N-(2-((2-(methylamino)-2-oxoethyl)thio)-4-phenylthiazol-5-yl)benzamide
  • 3,4-difluoro-N-(2-((2-(methylamino)-2-oxoethyl)thio)-4-phenylthiazol-5-yl)benzamide
  • N-methyl-2-((4-phenyl-5-(2-(p-tolyloxy)acetamido)thiazol-2-yl)thio)acetamide
  • 2-(2-fluorophenoxy)-N-(2-((2-(methylamino)-2-oxoethyl)thio)-4-phenylthiazol-5-yl)acetamide