2-Propenoic acid,ethenyl ester

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Names

[ CAS No. ]:
2177-18-6

[ Name ]:
2-Propenoic acid,ethenyl ester

[Synonym ]:
Ethenyl acrylate
ethenyl 2-propenoate
2-propenoic acid,ethenyl ester
acrylic acid,vinyl ester
ethenyl prop-2-enoate
Propenoic acid ethenyl ester
EINECS 218-538-1
3-Oxahexa-1,5-diene-4-one

Chemical & Physical Properties

[ Density]:
0.936g/cm3

[ Boiling Point ]:
91.5ºC at 760mmHg

[ Molecular Formula ]:
C5H6O2

[ Molecular Weight ]:
98.09990

[ Flash Point ]:
13.5ºC

[ Exact Mass ]:
98.03680

[ PSA ]:
26.30000

[ LogP ]:
0.85910

[ Vapour Pressure ]:
53.7mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.432(lit.)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UD3341000
CHEMICAL NAME :
2-Propenoic acid, ethenyl ester
CAS REGISTRY NUMBER :
2177-18-6
LAST UPDATED :
199806
DATA ITEMS CITED :
5

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0529778-1
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0529778-1 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
90 uL/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Behavioral - somnolence (general depressed activity) Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0529778-1
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1450 ppm/4H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - corneal damage Lungs, Thorax, or Respiration - other changes Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0529778-1

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H300-H315-H318-H331

[ Precautionary Statements ]:
P210-P261-P264-P280-P301 + P310-P305 + P351 + P338

[ Hazard Codes ]:
F,T

[ Risk Phrases ]:
11-25-34

[ Safety Phrases ]:
S9;S16;S26;S45;S36/S37/S39

[ RIDADR ]:
UN 3286 3/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
UD3341000

[ HS Code ]:
2915320000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • ethene
  • Acrylic acid
  • 3-Chloropropionic acid vinyl ester
  • Acetylene
  • bis(ethenyl)mercury
  • vinyl acetate

DownStream

  • N-OCTYL ACRYLATE
  • 2,2-Dimethoxyethanol
  • Hexyl acrylate
  • chloro(2-oxoethyl)mercury
  • Acrylic acid
  • phenethyl acrylate
  • butyl acrylate
  • Benzyl acrylate
  • 3-Chloropropionic acid vinyl ester
  • 1,2-dibromoethyl prop-2-enoate

Customs

[ HS Code ]: 2916129000

[ Summary ]:
2916129000 other esters of acrylic acid VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Covalent Incorporation of Trehalose within Hydrogels for Enhanced Long-Term Functional Stability and Controlled Release of Biomacromolecules.

Adv. Healthc. Mater. 4 , 1802-12, (2015)

Hydrogels with covalently incorporated trehalose are synthesized using thiol-ene Michael addition. Trehalose hydrogels afford prolonged stabilization and -controlled release of model enzymes in vitro ...


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Related Compounds

  • 2-Methyl-2-propenoic acid,ethenyl ester
  • 2-Propenoic acid, ethenyl ester, homopolymer
  • 2-Propenoic acid, 3-phenyl-, ethenyl ester, homopolymer
  • 2-Propenoic acid,3-phenyl-, ethenyl ester
  • 2-Propenoic acid, 3-(3,4-dihydroxyphenyl)-, ethenyl ester, (2E)- (9CI)
  • ethenyl 3-(furan-2-yl)prop-2-enoate
  • 4-Amino-7-fluoro-2-(2-oxo-6-thioxopiperidin-3-yl)-3-thioxoisoindolin-1-one
  • Methyl 6-chloro-3-formylpyrazolo[1,5-a]pyridine-2-carboxylate
  • 2-Methyl-2-(1-phenylcyclopropyl)propanal
  • methyl (6S)-9-benzyl-9-azatricyclo[4.2.1.0,2,4]nonane-2-carboxylate
  • 3-(5-amino-1,2-oxazol-3-yl)-N,N-dimethylpyridin-2-amine
  • 5-(But-3-yn-2-yl)-2-methylphenol
  • 3-hydroxy-4-(1H-indol-3-yl)butanenitrile
  • 3,5-Dimethyl-1H,1'H-4,4'-bipyrazole hydrochloride
  • 1-(1-Ethoxyethyl)-3',5'-dimethyl-4,4'-bi-1H-pyrazole
  • Tert-butyl 1,4-dioxa-8-azaspiro[4.5]dec-6-ene-8-carboxylate
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