2-Propenoic acid,ethenyl ester

Modify Date: 2024-01-09 11:52:06

2-Propenoic acid,ethenyl ester Structure
2-Propenoic acid,ethenyl ester structure
 Common Name 2-Propenoic acid,ethenyl ester
CAS Number 2177-18-6 Molecular Weight 98.09990
Density 0.936g/cm3 Boiling Point 91.5ºC at 760mmHg
Molecular Formula C5H6O2 Melting Point N/A
MSDS Chinese USA Flash Point 13.5ºC
Symbol GHS02 GHS05 GHS06
GHS02, GHS05, GHS06		 Signal Word Danger

 Names

Name vinyl acrylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.936g/cm3
Boiling Point 91.5ºC at 760mmHg
Molecular Formula C5H6O2
Molecular Weight 98.09990
Flash Point 13.5ºC
Exact Mass 98.03680
PSA 26.30000
LogP 0.85910
Vapour Pressure 53.7mmHg at 25°C
Index of Refraction n20/D 1.432(lit.)

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UD3341000
CHEMICAL NAME :
2-Propenoic acid, ethenyl ester
CAS REGISTRY NUMBER :
2177-18-6
LAST UPDATED :
199806
DATA ITEMS CITED :
5

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0529778-1
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0529778-1 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
90 uL/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Behavioral - somnolence (general depressed activity) Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0529778-1
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1450 ppm/4H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - corneal damage Lungs, Thorax, or Respiration - other changes Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0529778-1

 Safety Information

Symbol GHS02 GHS05 GHS06
GHS02, GHS05, GHS06
Signal Word Danger
Hazard Statements H225-H300-H315-H318-H331
Precautionary Statements P210-P261-P264-P280-P301 + P310-P305 + P351 + P338
Hazard Codes F,T
Risk Phrases 11-25-34
Safety Phrases S9;S16;S26;S45;S36/S37/S39
RIDADR UN 3286 3/PG 2
WGK Germany 3
RTECS UD3341000
HS Code 2915320000

 Synthetic Route

ethene structure

ethene

CAS#:54509-73-8

Acrylic acid structure

Acrylic acid

CAS#:79-10-7

~0%

Tulipalin A structure

Tulipalin A

CAS#:547-65-9

2-Propenoic acid,ethenyl ester Structure

2-Propenoic aci...

CAS#:2177-18-6

Literature: NIPPON SHOKUBAI CO., LTD. Patent: WO2008/23823 A1, 2008 ; Location in patent: Page/Page column 81, 92 ;
3-Chloropropionic acid vinyl ester structure

3-Chloropropion...

CAS#:5309-67-1

~98%

2-Propenoic acid,ethenyl ester Structure

2-Propenoic aci...

CAS#:2177-18-6

Literature: Komarova, L. I.; Zhuravleva, E. I. Journal of Organic Chemistry USSR (English Translation), 1983 , p. 455 - 457 Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 3 p. 519 - 522
Acrylic acid structure

Acrylic acid

CAS#:79-10-7

Acetylene structure

Acetylene

CAS#:74-86-2

~%

2-Propenoic acid,ethenyl ester Structure

2-Propenoic aci...

CAS#:2177-18-6

Literature: BASF SE Patent: US2008/308765 A1, 2008 ; Location in patent: Page/Page column 6 ;
Acrylic acid structure

Acrylic acid

CAS#:79-10-7

~%

2-Propenoic acid,ethenyl ester Structure

2-Propenoic aci...

CAS#:2177-18-6

Literature: Shin-Etsu Vinyl Acetate Co., Ltd. Patent: US4425277 A1, 1984 ;
bis(ethenyl)mercury structure

bis(ethenyl)mercury

CAS#:1119-20-6

Acrylic acid structure

Acrylic acid

CAS#:79-10-7

~%

2-Propenoic acid,ethenyl ester Structure

2-Propenoic aci...

CAS#:2177-18-6

Literature: Foster,D.J.; Tobler,E. Journal of the American Chemical Society, 1961 , vol. 83, p. 851 - 855
vinyl acetate structure

vinyl acetate

CAS#:108-05-4

Acrylic acid structure

Acrylic acid

CAS#:79-10-7

~%

2-Propenoic acid,ethenyl ester Structure

2-Propenoic aci...

CAS#:2177-18-6

Literature: Shostakovskii,M.F. et al. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1967 , p. 2403 - 2405 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1967 , # 11 p. 2526 - 2530

 Customs

HS Code 2916129000
Summary 2916129000 other esters of acrylic acid VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Articles1

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 Synonyms

Ethenyl acrylate
ethenyl 2-propenoate
2-propenoic acid,ethenyl ester
acrylic acid,vinyl ester
ethenyl prop-2-enoate
Propenoic acid ethenyl ester
EINECS 218-538-1
3-Oxahexa-1,5-diene-4-one
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