(4-Nitrophenyl)boronic acid

Suppliers

Names

[ Name ]:
(4-Nitrophenyl)boronic acid

[Synonym ]:
Phenylboronic Acid,9
(4-Nitrophenyl)boronic acid
4-Nitrobenzeneboronic acid p-Nitrophenylboronic acid p-nitro-benzeneboronic acid
para-nitrophenylboronic acid
phenylboronic acid pinacol ester
4-Nitrobenzeneboronic Acid
MFCD00161360
boronic acid,b-(4-nitrophenyl)
4-Borononitrobenzene
Boronic acid, B-(4-nitrophenyl)-
p-nitrophenylboronic acid
4-Nitrophenylboronic Acid

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
373.7±44.0 °C at 760 mmHg

[ Melting Point ]:
285-290°C (dec.)

[ Molecular Formula ]:
C₆H₆BNO₄

[ Molecular Weight ]:
166.93

[ Flash Point ]:
179.8±28.4 °C

[ Exact Mass ]:
167.038986

[ PSA ]:
86.28000

[ LogP ]:
1.32

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.574

[ Storage condition ]:
2~8℃

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1-Iodo-4-nitrobenzene
Bis(pinacolato)diboron
1-Bromo-4-nitrobenzene
Phenylboronic acid
4-Chloronitrobenzene
Ethanoic anhydride
trifluoro(4-nitrophenyl)borate

DownStream

5-Nitro-2-phenylpyridine
3-Fluoronitrobenzene
1-Fluoro-4-nitrobenzene
4-Nitroaniline
pnb
4,4,5,5-Tetramethyl-2-(4-nitrophenyl)-1,3,2-dioxaborolane
4'-Nitro-4-biphenylcarboxylic acid
4-Nitrobenzonitrile
4H-1-BENZOPYRAN-4-ONE, 2-(4-NITROPHENYL)-
2-(4-Nitrophenyl)-2,3-dihydro-4H-1-benzopyran-4-one

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Ruthenium(0)-catalyzed sp3 C-H bond arylation of benzylic amines using arylboronates.

Org. Lett. 7th ed., 14 , 1930-1933, (2012)

A Ru-catalyzed direct arylation of benzylic sp(3) carbons of acyclic amines with arylboronates is reported. This highly regioselective and efficient transformation can be performed with various combin...

A new access to 3-substituted-1(2H)-isoquinolone by tandem palladium-catalyzed intramolecular aminocarbonylation annulation.

Org. Biomol. Chem. 13th ed., 10 , 2683-2691, (2012)

An original tribromide derivative based, palladium-catalyzed synthesis of 3-substituted-1(2H)-isoquinolone is described based on a regioselective Suzuki-Miyaura C-C coupling on o-halo-(2,2-dihalovinyl...

Copper-mediated sequential cyanation of aryl C-B and arene C-H bonds using ammonium iodide and DMF.

J. Am. Chem. Soc. 5th ed., 134 , 2528-2531, (2012)

The cyanation of aromatic boronic acids, boronate esters, and borate salts was developed under copper-mediated oxidative conditions using ammonium iodide and DMF as the source of nitrogen and carbon a...

3-Fluoro-4-nitrophenylboronic acid
(3-Methyl-4-nitrophenyl)boronic acid
2-Fluoro-4-nitrophenylboronic acid
(2-methoxy-4-nitrophenyl)boronic acid
[3-(dimethoxymethyl)-4-nitrophenyl]boronic acid
(3-Formyl-4-nitrophenyl)boronic acid
methyl 1-(4-nitrophenyl)-1H-pyrazole-4-carboxylate
1-(4-Benzylpiperazin-1-yl)-2-(naphthalen-1-yl)ethanone hydrochloride
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Ser-Gln-Gly
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CID 14595060
2-Ethyl-3-fluoropyridine
4-Ethyl-2-(methylamino)phenol
(1R,2R)-2-Ethynylcycloheptan-1-ol

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