(4-Nitrophenyl)boronic acid
(4-Nitrophenyl)boronic acid structure
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Common Name | (4-Nitrophenyl)boronic acid | ||
|---|---|---|---|---|
| CAS Number | 24067-17-2 | Molecular Weight | 166.93 | |
| Density | 1.4±0.1 g/cm3 | Boiling Point | 373.7±44.0 °C at 760 mmHg | |
| Molecular Formula | C6H6BNO4 | Melting Point | 285-290°C (dec.) | |
| MSDS | USA | Flash Point | 179.8±28.4 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Ruthenium(0)-catalyzed sp3 C-H bond arylation of benzylic amines using arylboronates.
Org. Lett. 7th ed., 14 , 1930-1933, (2012) A Ru-catalyzed direct arylation of benzylic sp(3) carbons of acyclic amines with arylboronates is reported. This highly regioselective and efficient transformation can be performed with various combinations of N-(2-pyridyl) substituted benzylamines and arylbo... |
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A new access to 3-substituted-1(2H)-isoquinolone by tandem palladium-catalyzed intramolecular aminocarbonylation annulation.
Org. Biomol. Chem. 13th ed., 10 , 2683-2691, (2012) An original tribromide derivative based, palladium-catalyzed synthesis of 3-substituted-1(2H)-isoquinolone is described based on a regioselective Suzuki-Miyaura C-C coupling on o-halo-(2,2-dihalovinyl)-benzene followed by a palladium catalyzed amination-carbo... |
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Copper-mediated sequential cyanation of aryl C-B and arene C-H bonds using ammonium iodide and DMF.
J. Am. Chem. Soc. 5th ed., 134 , 2528-2531, (2012) The cyanation of aromatic boronic acids, boronate esters, and borate salts was developed under copper-mediated oxidative conditions using ammonium iodide and DMF as the source of nitrogen and carbon atom of the cyano unit, respectively. The procedure was succ... |
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B-ring-modified isocombretastatin A-4 analogues endowed with interesting anticancer activities.
ChemMedChem 12th ed., 6 , 2179-2191, (2011) A novel class of isocombretastatin A-4 (isoCA-4) analogues with modifications at the 3'-position of the B-ring by replacement with C-linked substituents was studied. Exploration of the structure-activity relationships of theses analogues led to the identifica... |
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Synthesis of bromo-, boryl-, and stannyl-functionalized 1,2-bis(trimethylsilyl)benzenes via Diels-Alder or C-H activation reactions.
J. Org. Chem. 7th ed., 77 , 3518-3523, (2012) 1,2-Bis(trimethylsilyl)benzenes are key starting materials for the synthesis of benzyne precursors, Lewis acid catalysts, and certain luminophores. We have developed efficient, high-yield routes to functionalized 4-R-1,2-bis(trimethylsilyl)benzenes, starting ... |
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P1-substituted symmetry-based human immunodeficiency virus protease inhibitors with potent antiviral activity against drug-resistant viruses.
J. Med. Chem. 54 , 7094-7104, (2011) Because there is currently no cure for HIV infection, patients must remain on long-term drug therapy, leading to concerns over potential drug side effects and the emergence of drug resistance. For this reason, new and safe antiretroviral agents with improved ... |
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Efficient palladium-catalyzed Suzuki-Miyaura cross-coupling of iodoethynes with arylboronic acids under aerobic conditions J. Tang, et al.,
Synthesis 17 , 2789-2795, (2011)
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Cu(acac)2-catalyzed N-arylations of phenylurea with arylboronic acid Gavade, S.; et al.
Synth. Commun. 11th ed., 42 , 1704-1714, (2012)
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Tetrahedron 63 , 6131, (2007)
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An efficient copper-catalyzed one-pot synthesis of diaryl thioethers by coupling of arylboronic acids with potassium ethyl xanthogenate under mild conditions Wang, L.; et al.
Synlett 20 , 3041-3045, (2011)
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