2,6-Diphenylphenol

Suppliers

Names

[ Name ]:
2,6-Diphenylphenol

[Synonym ]:
m-Terphenyl-2'-ol
1,1':3',1''-Terphenyl-2'-ol
2,6-Ph2C6H3OH
EINECS 219-401-9
2,6-Diphenylphenol
2,5-DIMETHYL-2,5-BIS-(BENZOYLPEROXY)-HEXANE
[1,1':3',1''-Terphenyl]-2'-ol
[m-Terphenyl]-2'-ol
QR BR& FR
2'-hydroxy[1,1':3',1"]terphenyl
MFCD00009716
2'-Hydroxy-m-terphenyl
2,6-diphenyl-phenol

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
384.8±11.0 °C at 760 mmHg

[ Melting Point ]:
101-103 °C(lit.)

[ Molecular Formula ]:
C₁₈H₁₄O

[ Molecular Weight ]:
246.303

[ Flash Point ]:
183.2±11.1 °C

[ Exact Mass ]:
246.104462

[ PSA ]:
20.23000

[ LogP ]:
4.68

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.626

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2,6-di(cyclohexen-1-yl)cyclohexan-1-one
2,6-di(cyclohexylidene)cyclohexan-1-one
2-cyclohexylidene-6-(1-cyclohexen-1-yl)cyclohexan-1-one
2,6-Dichlorophenol
Phenyltriethoxysilane
Phenylboronic acid
Iodobenzene
Bromobenzene
Phenol

DownStream

4-Amino-2,6-diphenylphenol
4-(2,6-diphenylphenoxy)-2,6-diphenylphenol
para-Terphenyl
2,6-diphenylcyclohexa-2,5-diene-1,4-dione
1,5,1',5'-tetraphenyl-[3,3']bicyclohexa-1,4-dienylidene-6,6'-dione
4-[(4-hydroxy-3,5-diphenylphenyl)methyl]-2,6-diphenylphenol
4-Nitro-2,6-diphenylphenol
2,6-DIPHENYL-4-(2,4,6-TRIPHENYL-1-PYRIDINIO)PHENOLATE
4,4''-Dinitro-p-terphenyl
4-methoxy-2,6-diphenylphenol

Articles

Variation of electronic transitions and reduction potentials of cerium(IV) complexes.

Dalton Trans. 43(43) , 16197-206, (2014)

The trivalent compound K[Ce[N(SiHMe2)2]4] was synthesized and oxidized, providing a convenient route to the reported cerium(IV) compound Ce[N(SiHMe2)2]4. Protonolysis reactions of Ce[N(SiHMe2)2]4 with...

Synthesis of group 1 metal 2,6-diphenylphenoxide complexes [M(OC6H3Ph2-2,6)] (M = Li, Na, K, Rb, Cs) and structures of the solvent-free complexes [Rb(OC6H3Ph2-2,6)]x and [Cs(OC6H3Ph2-2,6)x: one-dimensional extended arrays of metal aryloxides.

Inorg. Chem. 42(19) , 6089-94, (2003)

Reaction of 2,6-diphenylphenol (HOC(6)H(3)Ph(2)-2,6) with (n)BuLi, NaH, KH, or Rb or Cs metal in benzene gives the solvent-free complexes [M(OAr)]x in excellent yield. The complex [Rb(OC(6)H(3)Ph(2)-2...

Clathrate formation from octaazaphthalocyanines possessing bulky phenoxyl substituents: a new cubic crystal containing solvent-filled, nanoscale voids.

Chemistry 14(16) , 4810-5, (2008)

The synthesis of octaazaphthalocyanine (AzaPc) derivatives, with bulky phenoxyl substituents placed at eight peripheral positions and containing either H(+), Ni(2+) or Zn(2+) ions in their central cav...