2,6-Diphenylphenol

2,6-Diphenylphenol Structure
2,6-Diphenylphenol structure
Common Name 2,6-Diphenylphenol
CAS Number 2432-11-3 Molecular Weight 246.303
Density 1.1±0.1 g/cm3 Boiling Point 384.8±11.0 °C at 760 mmHg
Molecular Formula C18H14O Melting Point 101-103 °C(lit.)
MSDS Chinese USA Flash Point 183.2±11.1 °C
Symbol GHS07
GHS07
Signal Word Warning

Variation of electronic transitions and reduction potentials of cerium(IV) complexes.

Dalton Trans. 43(43) , 16197-206, (2014)

The trivalent compound K[Ce[N(SiHMe2)2]4] was synthesized and oxidized, providing a convenient route to the reported cerium(IV) compound Ce[N(SiHMe2)2]4. Protonolysis reactions of Ce[N(SiHMe2)2]4 with tert-butanol, substituted benzyl alcohols, and 2,6-dipheny...

Synthesis of group 1 metal 2,6-diphenylphenoxide complexes [M(OC6H3Ph2-2,6)] (M = Li, Na, K, Rb, Cs) and structures of the solvent-free complexes [Rb(OC6H3Ph2-2,6)]x and [Cs(OC6H3Ph2-2,6)x: one-dimensional extended arrays of metal aryloxides.

Inorg. Chem. 42(19) , 6089-94, (2003)

Reaction of 2,6-diphenylphenol (HOC(6)H(3)Ph(2)-2,6) with (n)BuLi, NaH, KH, or Rb or Cs metal in benzene gives the solvent-free complexes [M(OAr)]x in excellent yield. The complex [Rb(OC(6)H(3)Ph(2)-2,6)](x)() exhibits a ladderlike structure in the solid stat...

Clathrate formation from octaazaphthalocyanines possessing bulky phenoxyl substituents: a new cubic crystal containing solvent-filled, nanoscale voids.

Chemistry 14(16) , 4810-5, (2008)

The synthesis of octaazaphthalocyanine (AzaPc) derivatives, with bulky phenoxyl substituents placed at eight peripheral positions and containing either H(+), Ni(2+) or Zn(2+) ions in their central cavity, is described. The required precursors, derivatives of ...

Synthesis, structure, and magnetic studies of manganese-oxygen clusters of reduced coordination number, featuring an unchelated, 5-coordinate octanuclear manganese cluster with water-derived oxo ligands.

Inorg. Chem. 51(19) , 10095-104, (2012)

The synthesis of reduced coordination (less than 6), unchelated manganese oxygen cluster systems is described. Addition of phenols to Mn(NR(2))(2) (R = SiMe(3)) results in protolytic amide ligand replacement, and represents the primary entry into the describe...