dichlorotriphenylphosphorane

Names

[ Name ]:
dichlorotriphenylphosphorane

[Synonym ]:
MFCD00010359
Dichlorotriphenylphosphorane
triphenylphosphine dichloride
triphenyldichlorophosphorane
triphenylphosphine chloride

Chemical & Physical Properties

[ Melting Point ]:
85ºC

[ Molecular Formula ]:
C₁₈H₁₅Cl₂P

[ Molecular Weight ]:
333.19100

[ Flash Point ]:
68 °F

[ Exact Mass ]:
332.02900

[ PSA ]:
13.59000

[ LogP ]:
4.82380

[ Water Solubility ]:
Reacts with water.

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H314-H350

[ Precautionary Statements ]:
P201-P210-P280-P305 + P351 + P338-P310

[ Hazard Codes ]:
F: Flammable;T: Toxic;

[ Risk Phrases ]:
R45;R11;R34

[ Safety Phrases ]:
53-26-36/37/39-45-16

[ RIDADR ]:
UN 2925

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Development of new N-Arylbenzamides as STAT3 Dimerization Inhibitors.

MedChemComm 4(6) , 932-941, (2013)

The O-tosylsalicylamide S3I-201 (10) was used as a starting point for design and synthesis of novel STAT-3 dimerization inhibitors with improved drug-like qualities. The phosphonic acid 12d and salicy...

Simple and convenient synthesis of tertiary benzanilides using dichlorotriphenylphosphorane. Azumaya I, et al.

Tetrahedron 59(13) , 2325-31, (2003)

Cleavage of carboxylic acid esters to acid chlorides with dichlorotriphenylphosphorane. Burton DKJ and Koppes WM.

J. Org. Chem. 40(21) , 3026-3032., (1975)

dichlorotriphenylphosphorane
3-(3,3-Dimethylcyclopentyl)oxolane-2,5-dione
3-(3-Ethoxy-2-methoxyphenyl)-1,2-oxazol-5-amine
O-{[2-(propan-2-yl)-1,3-thiazol-5-yl]methyl}hydroxylamine
2-(1,3-dimethyl-1H-pyrazol-4-yl)-3,3-difluoropropan-1-amine
4-[1-(1-Hydroxyethyl)cyclopropyl]-2,6-dimethylphenol
tert-butyl N-[4-(2-amino-1,3-oxazol-5-yl)phenyl]carbamate
Tert-butyl 2-(1-hydroxy-2-methoxy-2-oxoethyl)morpholine-4-carboxylate
3-(1-ethyl-1H-pyrazol-3-yl)-3-methylbutanoic acid
1-[2-Methyl-4-(pyrrolidin-1-yl)butan-2-yl]cyclopropan-1-amine
tert-butyl N-[3-(aminomethyl)-4-hydroxy-3-methylbutan-2-yl]-N-methylcarbamate

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