ALPHA-(TRIMETHYLSILYLOXY)PHENYLACETONIT&

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Names

[ CAS No. ]:
25438-37-3

[ Name ]:
ALPHA-(TRIMETHYLSILYLOXY)PHENYLACETONIT&

[Synonym ]:
Phenyl-trimethylsilanyloxy-acetonitrile
Acetonitrile,2-phenyl-2-trimethylsilyloxy
MFCD02295646
2-phenyl-2-trimethylsiloxyethanenitrile

Chemical & Physical Properties

[ Density]:
0.978 g/mL at 25ºC(lit.)

[ Boiling Point ]:
91ºC0.5 mm Hg(lit.)

[ Molecular Formula ]:
C11H15NOSi

[ Molecular Weight ]:
205.32800

[ Flash Point ]:
221 °F

[ Exact Mass ]:
205.09200

[ PSA ]:
33.02000

[ LogP ]:
3.10278

[ Vapour Pressure ]:
0.021mmHg at 25°C

[ Index of Refraction ]:
0.978

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H332

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S23;S27;S45;S36/S37/S39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Trimethylsilyl cyanide
  • Benzaldehyde
  • Chlorotrimethylsilane
  • POTASSIUM CYANIDE
  • Mandelonitrile
  • trans-Stilbene
  • N-Methylaniline
  • Hexamethyldisilazane
  • lithium,cyanide
  • HYDROGEN CYANIDE

DownStream

  • (-)-norephedrine
  • (1S,2R)-(+)-Norephedrine
  • Cathine
  • Benzoyl cyanide
  • 1-phenyl(trimethylsiloxy)ethylene
  • Benzamide
  • Acetophenone
  • 1-hydroxy-1-phenylacetone
  • 2-Hydroxypropiophenone
  • 4-Chloro-1-oxo-1-phenylbutane

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Related Compounds

  • alpha-tocopherol 5-n-butyl-2-pyridinecarboxylate
  • alpha-ethyl, alpha-methyl-thiobutyrolactone
  • alpha;-(TETRAHYDRO-4,6-DIOXO-2-THIOXO-5(2H)PYRIMIDINYLIDENE)-o-TOLUIC ACID
  • alpha-d-Glucopyranose, 1,6-bis(dihydrogen phosphate), tetrasodium salt
  • alpha-(p-Methylbenzyl)-2-thenylamine hydrochloride
  • alpha-d-Glucopyranose, 1,6-bis(dihydrogen phosphate), diammonium salt
  • 5-Tert-butyl-3-hydroxypyrrolidin-2-one
  • 1-Methyl-4,8-dioxa-1,10-diazaspiro[5.5]undecane
  • 3-Hydroxy-4-(2,2,2-trifluoroethoxy)-2,3-dihydro-1lambda6-benzothiophene-1,1-dione
  • 4-Chloro-3-hydroxy-2,3-dihydro-1lambda6-benzothiophene-1,1-dione
  • 1-(Chlorosulfonyl)piperidin-4-yl acetate
  • tert-butyl 6-(trifluoroacetyl)-3,4-dihydro-2H-oxazine-4-carboxylate
  • 1-(Carboxy)pyrrolidin-3-yl acetate
  • 2,5-Dichloro-1,3-benzothiazole-4-sulfonyl chloride
  • 5-[(Tert-butoxy)carbonyl]-1,1-difluoro-5-azaspiro[2.3]hexane-4-carboxylic acid
  • 5-Amino-2-(1-{[(tert-butoxy)carbonyl]amino}ethyl)-1,3-thiazole-4-carboxylic acid
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