4-methoxybenzyloxycarbonyl azide

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Names

[ CAS No. ]:
25474-85-5

[ Name ]:
4-methoxybenzyloxycarbonyl azide

[Synonym ]:
EINECS 247-017-1
p-methoxy-carbobenzoxy azide
4-methoxy-benzyloxycarbonyl azide
(p-methoxyphenyl)methoxycarbonylazide
[(p-methoxybenzyl)oxy]carbonylazide
MFCD00001988
4-methoxybenzyl carbonazidate
4-methoxybenzyl azidoformate
[(4-Methoxyphenyl)methoxy]carbonylazide
p-Methoxybenzylazidoformate

Chemical & Physical Properties

[ Melting Point ]:
30-32ºC(lit.)

[ Molecular Formula ]:
C9H9N3O3

[ Molecular Weight ]:
207.18600

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
207.06400

[ PSA ]:
85.28000

[ LogP ]:
2.09486

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS03, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H272-H302 + H312 + H332

[ Precautionary Statements ]:
P220-P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R5

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
UN 1479 5.1/PG 2

[ WGK Germany ]:
3

[ HS Code ]:
2927000090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-METHOXYBENZYL CARBAZATE
  • p-methoxybenzyl phenyl carbonate

DownStream

  • 2-[(4-methoxyphenyl)methoxycarbonylamino]acetic acid

Customs

[ HS Code ]: 2927000090

[ Summary ]:
2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Synthesis of tritium-labelled isopenicillin N, penicillin N and 6-aminopenicillanic acid.

Biochem. J. 151(3) , 729-39, (1975)

1. Phenoxymethylpenicillin sulphoxide 4-methoxybenzyl ester was labelled with 3H in its 2-beta-methyl group. Its specific radioactivity was 362 mCi/mmol. 2. Removal of the side chain of this compound ...


More Articles

Related Compounds

  • 4-Methoxybenzyl carbonochloridate
  • 4-methoxybenzyloxycarbonyl-asparaginyl-leucyl-glycine ethyl ester
  • Z(OMe)-His-N3
  • N-(4-methoxybenzyloxycarbonyl)-tyrosinol
  • N-(4-Methoxybenzyloxycarbonyl)-O-benzyl-L-serine
  • N,O-BIS(4-METHOXYBENZYLOXYCARBONYL)-(S)-2-AMINO-3-(4-HYDROXYPHENYL)-PROPIONITRILE
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
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  • 3-Amino-1-[3-(methoxymethyl)phenyl]propan-1-ol
  • Ethyl 3-(4-bromo-2-methylphenyl)-1,2,4-oxadiazole-5-carboxylate
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1-(5-aminopyridin-2-yl)-3-phenyl-4,5-dihydro-1H-pyrazol-5-one
  • 5-[(Hex-1-yn-3-yl)amino]pyrazine-2-carboxylic acid
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol