Tricyclohexylphosphine

Suppliers

Names

[ Name ]:
Tricyclohexylphosphine

[Synonym ]:
Phosphine, tricyclohexyl-
triscyclohexylphosphine
Tricyclohexyl-phosphane
Tricyclohexylphosphine solution
EINECS 220-069-2
Tricyclohexylphosphine
PCy3
Phosphine,tricyclohexyl
tricyclohexylphosphan
MFCD00003853
bistricyclohexylphosphine
Tricyclohexyl Phosphine

Chemical & Physical Properties

[ Density]:
0.909 g/mL at 25 °C

[ Boiling Point ]:
383.4±9.0 °C at 760 mmHg

[ Melting Point ]:
81-83 °C(lit.)

[ Molecular Formula ]:
C₁₈H₃₃P

[ Molecular Weight ]:
280.428

[ Flash Point ]:
195.6±25.0 °C

[ Exact Mass ]:
280.231995

[ PSA ]:
13.59000

[ LogP ]:
7.00

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Storage condition ]:
−20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H304-H315-H319-H335-H336-H361d-H373

[ Precautionary Statements ]:
P210-P261-P281-P301 + P310-P305 + P351 + P338-P331

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S36/37-S62-S37/39-S36-S33-S29-S16

[ RIDADR ]:
UN 2056 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.0

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Tricyclohexylphosphine oxide
Triphenylphosphine
Cyclohexanol
Chlorocyclohexane
O-cyclohexyl 1H-imidazole-1-carbothioate
Dicyclohexylphosphinous chloride
Tricyclohexylphosphine Carbon Disulfide
Bromocyclohexane
Cr(CO)3{P(C6H11)3}2
Cycloheptatriene

DownStream

Bis(tricyclohexylphosphine)palladium(0)
1,2,3,4,5-Pentaphenyl-1'-(di-tert-butylphosphino)ferrocene
(Cy3P)2Pd(Ph)Br
sodium chloride
Diborane
trans-dihydridobis(tricyclohexylphosphine)platinum
fac-[(η1-(tricyclohexylphosphine))(η2-(1,10-phenanthroline))Mo(CO)3]
Fullerene-C60
9H-pyrido[2,3-b]indole

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Synthesis and Catalytic Performance of Hierarchically Porous MIL-100(Fe)@polyHIPE Hybrid Membranes.

Macromol. Rapid Commun. 36 , 1605-11, (2015)

Metal-organic frameworks (MOFs) nanoparticles in combination with a nonionic surfactant (Pluronic L-121) are used to stabilize dicyclopentadiene (DCPD)-in-water high internal phase emulsions (HIPEs). ...

Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines.

Dalton Trans. 43(42) , 15997-6005, (2014)

Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while main...

Formation of nickeladihydropyran by oxidative addition of cyclopropyl ketone. Key intermediate in nickel-catalyzed cycloaddition.

J. Am. Chem. Soc. 128(6) , 5350-5351, (2006)

Cyclopropyl phenyl ketone underwent oxidative addition to Ni(PCy3) generated from Ni(cod)2 and PCy3 to give a nickeladihydropyran, which is a key intermediate for the Ni(0)-catalyzed homo- or heterocy...