Tricyclohexylphosphine

Tricyclohexylphosphine Structure
Tricyclohexylphosphine structure
Common Name Tricyclohexylphosphine
CAS Number 2622-14-2 Molecular Weight 280.428
Density 0.909 g/mL at 25 °C Boiling Point 383.4±9.0 °C at 760 mmHg
Molecular Formula C18H33P Melting Point 81-83 °C(lit.)
MSDS Chinese USA Flash Point 195.6±25.0 °C
Symbol GHS02 GHS07 GHS08
GHS02, GHS07, GHS08
Signal Word Danger

Synthesis and Catalytic Performance of Hierarchically Porous MIL-100(Fe)@polyHIPE Hybrid Membranes.

Macromol. Rapid Commun. 36 , 1605-11, (2015)

Metal-organic frameworks (MOFs) nanoparticles in combination with a nonionic surfactant (Pluronic L-121) are used to stabilize dicyclopentadiene (DCPD)-in-water high internal phase emulsions (HIPEs). The resulting HIPEs containing the MIL-100(Fe) nanoparticle...

Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines.

Dalton Trans. 43(42) , 15997-6005, (2014)

Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while maintaining good selectivity and atom economy. The catalytic sy...

Formation of nickeladihydropyran by oxidative addition of cyclopropyl ketone. Key intermediate in nickel-catalyzed cycloaddition.

J. Am. Chem. Soc. 128(6) , 5350-5351, (2006)

Cyclopropyl phenyl ketone underwent oxidative addition to Ni(PCy3) generated from Ni(cod)2 and PCy3 to give a nickeladihydropyran, which is a key intermediate for the Ni(0)-catalyzed homo- or heterocycloaddition to give cyclopentane compounds having two carbo...

Synlett , 3001, (2006)

Synlett , 3167, (2006)