n-methyl-4,4'-methylenedianiline

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Names

[ CAS No. ]:
26628-67-1

[ Name ]:
n-methyl-4,4'-methylenedianiline

[Synonym ]:
4-((4-Aminophenyl)methyl)-N-methylbenzenamine
N-Methyl-4,4'-Methylendiamin
N-methyl-4,4'-diaminodiphenylmethane
4-(4-methylaminobenzyl)phenylamine
N-Methyl-4,4'-methylenedianiline
N-methyl-4,4'-MDA
ANILINE,N-METHYL-4,4'-METHYLENEDI
MFCD00192304

Chemical & Physical Properties

[ Density]:
1.113g/cm3

[ Boiling Point ]:
390.8ºC at 760mmHg

[ Melting Point ]:
61-63ºC(lit.)

[ Molecular Formula ]:
C14H16N2

[ Molecular Weight ]:
212.29000

[ Flash Point ]:
224.5ºC

[ Exact Mass ]:
212.13100

[ PSA ]:
38.05000

[ LogP ]:
3.55550

[ Vapour Pressure ]:
2.58E-06mmHg at 25°C

[ Index of Refraction ]:
1.648

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BY5700000
CHEMICAL NAME :
Aniline, N-methyl-4,4'-methylenedi-
CAS REGISTRY NUMBER :
26628-67-1
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C14-H16-N2
MOLECULAR WEIGHT :
212.32
WISWESSER LINE NOTATION :
ZR D1R DM1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
10 ug/plate
REFERENCE :
CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 42,3475,1982

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
BY5700000

[ HS Code ]:
2921590090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-((1H-BENZO[D][1,2,3]TRIAZOL-1-YL)METHYL)ANILINE
  • N-Methylaniline
  • 1H-BENZOTRIAZOLE-1-METHANOL
  • diazomethane
  • 4-methylaminophenylmercury chloride
  • Formaldehyde

DownStream

Customs

[ HS Code ]: 2921590090

[ Summary ]:
2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Disposition and metabolism of the carcinogen reduced Michler's ketone in rats.

Cancer Res. 42(9) , 3475-9, (1982)

Studies on the in vivo and in vitro disposition of 4,4'-[14C]-methylenebis(N,N-dimethyl)benzamine (reduced Michler's ketone, RMK) were performed. Osborne-Mendel rats retained, after 24 hr, 78% of a p....


More Articles

Related Compounds

  • N-Methyl-4,4'-methylenedianiline
  • N-methyl-4,4'-bipyridinium diodide
  • 4,4'-METHYLENEBIS(N-METHYLANILINE)
  • tetra-N-methyl-4,4'-(1H-[1,2,3]triazol-4-ylmethanediyl)-bis-aniline
  • tetra-N-methyl-4,4'-[5-(3-chloro-phenyl)-oxazole-2,4-diyl]-bis-aniline
  • tetra-N-methyl-4,4'-(3-methylsulfanyl-[1,2,4]triazine-5,6-diyl)-bis-aniline
  • 3-[(2-Nitrophenyl)methylidene]azetidine
  • 5-(5-bromo-2-cyclopropylpyrimidin-4-yl)-1H-imidazol-2-amine
  • 1-(3,5-Dichloro-4-fluorophenyl)methanamine hydrochloride
  • Lithium(1+)4-[(tert-butoxy)carbonyl]-octahydrofuro[3,2-b]pyridine-6-carboxylate
  • 2-Aminocyclobutane-1,3-diolhydrochloride
  • 2,2-Difluoro-3-(3-fluoro-4-nitrophenyl)propanoic acid
  • rac-(1R,3S)-3-(4-bromo-3-fluorophenyl)-2,2-dimethylcyclopropan-1-amine
  • 6-(4-Bromophenyl)hex-3-en-2-one
  • 3-(2-Bromo-6-chlorophenoxy)propan-1-amine
  • 2-{1-[2-(4-Bromophenyl)ethyl]cyclopropyl}ethan-1-amine
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